3,5-Dichlorophenylhydrazine hydrochloride synthesis
- Product Name:3,5-Dichlorophenylhydrazine hydrochloride
- CAS Number:63352-99-8
- Molecular formula:C6H7Cl3N2
- Molecular Weight:213.49
![Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-](/CAS/20210305/GIF/1000210-73-0.gif)
1000210-73-0
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63352-99-8
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Yield:-
Reaction Conditions:
with hydrogenchloride in 1,4-dioxane;methanol at 90; for 2 h;
Steps:
Conversion of oxamic adducts (1a-e) to hydrazines
General procedure: The adduct 1x was dissolved in methanol (x mL) to make 0.2 M solution, to this, was added 4 M hydrochloric acid in dioxane (x/2 mL). The dark solution was then stirred at reflux for 2 hours before removing from the heat. Once cool enough ~5-10 volumes of diethyl ether are added to create a profusion of fluffy solid which are filtered and washed to provide the hydrazine hydrochlorides.
References:
Browne, Duncan L.;Baxendale, Ian R.;Ley, Steven V. [Tetrahedron,2011,vol. 67,# 52,p. 10296 - 10303] Location in patent:supporting information; experimental part
19752-55-7
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63352-99-8
153 suppliers
$9.00/5g