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ChemicalBook CAS DataBase List 2-Ethylhexylamine
104-75-6

2-Ethylhexylamine synthesis

5synthesis methods
-

Yield:-

Reaction Conditions:

with chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II);urea;diphenylphosphinopropane in diethylene glycol dimethyl ether at 160; for 12 h;Autoclave;Inert atmosphere;

Steps:

2.3. General catalytic procedure for amination
General procedure: The autoclave was charged with 1-hexylalcohol (2.5 mmol) and urea (2.5 mmol) in 1mLdiglyme. [(Cp)RuCl(dppe)] (3percent mol) as catalyst, diphenylphosphinopropane (dppp)(0.07 mmol) as supporting ligand and 0.04 g K2CO3 as base was added. The autoclavewas closed, flushed with argon for 5 min and then temperature was adjusted at160 °C. After 12 h, the autoclave was cooled to room temperature and the productswere analyzed by gas chromatography.

References:

Dindar, Sara;Nemati Kharat, Ali [Journal of Coordination Chemistry,2020]

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