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ChemicalBook CAS DataBase List 2,4-DINITROBENZYL CHLORIDE
610-57-1

2,4-DINITROBENZYL CHLORIDE synthesis

4synthesis methods
-

Yield: 83%

Reaction Conditions:

Stage #1:dichloromethane with n-butyllithium in tetrahydrofuran;hexane at -100; for 0.333333 h;Inert atmosphere;
Stage #2:meta-dinitrobenzene in tetrahydrofuran;hexane at -100; for 0.00833333 h;Inert atmosphere;
Stage #3: with trifluorormethanesulfonic acid in tetrahydrofuran;hexane;water at -100 - 20;Inert atmosphere;

References:

Khutorianskyi, Viktor V.;Klepetá?ová, Blanka;Beier [Organic Letters,2019,vol. 21,# 14,p. 5443 - 5446] Location in patent:supporting information

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