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ChemicalBook CAS DataBase List 2,2,2-Trifluoroethylamine hydrochloride
373-88-6

2,2,2-Trifluoroethylamine hydrochloride synthesis

3synthesis methods
-

Yield:373-88-6 96.3%

Reaction Conditions:

with hydrogenchloride in ethanol;water at 25 - 50; for 1 h;Temperature;

Steps:

2

Add 100 g to a three-necked flaskEthanol and 33 gTrifluoroethylamine,At temperatures below 25 ° C, 35 g of saturated hydrochloric acid solution was slowly added dropwise,After the drop was completed, the temperature was raised to 50 ° C for one hour.The reaction solution in the system after the vacuum of 0.98MPa,The control temperature is 45 ± 5 ° C,After 5 hours of distillation under reduced pressure, the water and ethanol were removed,To give trifluoroethylamine hydrochloride 43. 5 g,The product yield was 96. 30%. The obtained trifluoroethylamine hydrochloride was a white powdery crystalline solid,The water content was 0.13%.

References:

CN105801428,2016,A Location in patent:Paragraph 0016; 0017

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