(1S, 2R)-2-(Benzyloxymethyl)-1-hydroxy-3-cyclopentene synthesis
- Product Name:(1S, 2R)-2-(Benzyloxymethyl)-1-hydroxy-3-cyclopentene
- CAS Number:110567-21-0
- Molecular formula:C13H16O2
- Molecular Weight:204.26
3587-60-8
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4984-82-1
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110567-21-0
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Yield:110567-21-0 73%
Reaction Conditions:
Stage #1: Benzyloxymethyl chloride;sodium cyclopentadienylide in tetrahydrofuran;N,N-dimethyl-formamide at -40; for 0.25 h;
Stage #2: with L-diisopinocampheylborane in tetrahydrofuran at -10; for 48 h;
Stage #3: with sodium hydroxide;dihydrogen peroxide at 20; for 12 h;Further stages.;
References:
Woll, Matthew G.;Fisk, John D.;LePlae, Paul R.;Gellman, Samuel H. [Journal of the American Chemical Society,2002,vol. 124,# 42,p. 12447 - 12452]
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39939-07-6
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110567-21-0
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3587-60-8
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$10.00/1g
110567-21-0
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$7.00/1g
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117641-39-1
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110567-21-0
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