ChemicalBook CAS DataBase List 1,7-DIBROMOHEPTANE

1,7-DIBROMOHEPTANE synthesis

6synthesis methods

Product Name:1,7-DIBROMOHEPTANE
CAS Number:4549-31-9
Molecular formula:C7H14Br2
Molecular Weight:257.99

629-30-1 Synthesis

629-30-1
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4549-31-9
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$12.00/1g

Yield:4549-31-9 48%

Reaction Conditions:

with phosphorus tribromide;triethylamine in diethyl ether at 0;

Steps:

1.A Step A:
To a solution of compound 1 (80.0 g, 605.0 mmol) in diethyl ether (1000 mL) two drops of triethylamine were added with stirring at 0°C. PBr₃(75.0 g, 277.1 mmol) was added over 1.5 hours and the reaction mixture was left overnight with stirring. Then the mass was poured onto ice (200.0 g), the ether layer was evaporated. The residue was distilled in an oil pump vacuum to give 75.0 g (291.0 mmol, 48%) of compound 2.

References:

YISSUM RESEARCH DEVELOPMENT COMPANY OF THE HEBREW UNIVERSITY OF JERUSALEM LTD.;BEN-SASSON, Shmuel;GROSS, Einav WO2019/175873, 2019, A1 Location in patent:Paragraph 0084-0086

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629-30-1 Synthesis

629-30-1
256 suppliers
$8.00/1g