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ChemicalBook >> CAS DataBase List >> Tiglic acid

Tiglic acid

Tiglic acid price.
  • $5 - $2483.25
  • Product name: Tiglic acid
  • CAS: 80-59-1
  • MF: C5H8O2
  • MW: 100.12
  • EINECS:201-295-0
  • MDL Number:MFCD00066864
  • Synonyms:E-2,3-DIMETHYLACRYLIC ACID;FEMA 3599;trans-2,3-Dimethylacrylic acid~(E)-2-Methyl-2-butenoic acid;TRANS-2-METHYL-2-BUTENOIC ACID 99+%;TiglicAcid,>98%;trans-2-Methyl-2-butenoicacid,97%;2-Butenoicacid,2-methyl-,(E)- ;2-methyl-(E)-2-butenoic acid
37 prices
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  • AK Scientific
  • Alfa Aesar
  • Ambeed
  • American Custom Chemicals Corporation
  • ApexBio Technology
  • Arctom
  • Biorbyt Ltd
  • Chem-Impex
  • ChemScene
  • Crysdot
  • Frontier Specialty Chemicals
  • Medical Isotopes, Inc.
  • Oakwood
  • Sigma-Aldrich
  • SynQuest Laboratories
  • TCI Chemical
  • TRC
  • Usbiological
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  • ManufacturerAK Scientific
  • Product number7388AF
  • Product descriptionTiglic Acid
  • Packaging1g
  • Price$14
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product number7388AF
  • Product descriptionTiglic Acid
  • Packaging5g
  • Price$21
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13905
  • Product descriptionTiglic acid, 98+%
  • Packaging25g
  • Price$39.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13905
  • Product descriptionTiglic acid, 98+%
  • Packaging100g
  • Price$74.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13905
  • Product descriptionTiglic acid, 98+%
  • Packaging500g
  • Price$352.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAmbeed
  • Product numberA368298
  • Product description(E)-2-Methylbut-2-enoicacid 98%
  • Packaging250mg
  • Price$5
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA368298
  • Product description(E)-2-Methylbut-2-enoicacid 98%
  • Packaging1g
  • Price$6
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA368298
  • Product description(E)-2-Methylbut-2-enoicacid 98%
  • Packaging5g
  • Price$8
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA368298
  • Product description(E)-2-Methylbut-2-enoicacid 98%
  • Packaging25g
  • Price$13
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberFFG0002116
  • Product descriptionTRANS-2,3-DIMETHYLACRYLIC ACID 95.00%
  • Packaging5G
  • Price$889.35
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberFFG0002116
  • Product descriptionTRANS-2,3-DIMETHYLACRYLIC ACID 95.00%
  • Packaging100G
  • Price$2483.25
  • Updated2021-12-16
  • Buy
  • ManufacturerApexBio Technology
  • Product numberC6879
  • Product descriptionTiglic Acid
  • Packaging100mg
  • Price$50
  • Updated2021-12-16
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  • ManufacturerArctom
  • Product numberCFN90969
  • Product descriptionTiglic Acid ≥98%
  • Packaging20mg
  • Price$30
  • Updated2021-12-16
  • Buy
  • ManufacturerBiorbyt Ltd
  • Product numberorb259531
  • Product descriptionTiglic Acid 98%
  • Packaging20mg
  • Price$153
  • Updated2021-12-16
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  • ManufacturerBiorbyt Ltd
  • Product numberorb259531
  • Product descriptionTiglic Acid 98%
  • Packaging1000mg
  • Price$187
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number22605
  • Product descriptionTiglicacid,≥98%(Assaybytitration,GC)Hazmat ≥98%(Assaybytitration,GC)
  • Packaging25G
  • Price$39.6
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 7388AF Tiglic Acid 1g $14 2021-12-16 Buy
AK Scientific 7388AF Tiglic Acid 5g $21 2021-12-16 Buy
Alfa Aesar A13905 Tiglic acid, 98+% 25g $39.65 2024-03-01 Buy
Alfa Aesar A13905 Tiglic acid, 98+% 100g $74.65 2024-03-01 Buy
Alfa Aesar A13905 Tiglic acid, 98+% 500g $352.65 2024-03-01 Buy
Ambeed A368298 (E)-2-Methylbut-2-enoicacid 98% 250mg $5 2021-12-16 Buy
Ambeed A368298 (E)-2-Methylbut-2-enoicacid 98% 1g $6 2021-12-16 Buy
Ambeed A368298 (E)-2-Methylbut-2-enoicacid 98% 5g $8 2021-12-16 Buy
Ambeed A368298 (E)-2-Methylbut-2-enoicacid 98% 25g $13 2021-12-16 Buy
American Custom Chemicals Corporation FFG0002116 TRANS-2,3-DIMETHYLACRYLIC ACID 95.00% 5G $889.35 2021-12-16 Buy
American Custom Chemicals Corporation FFG0002116 TRANS-2,3-DIMETHYLACRYLIC ACID 95.00% 100G $2483.25 2021-12-16 Buy
ApexBio Technology C6879 Tiglic Acid 100mg $50 2021-12-16 Buy
Arctom CFN90969 Tiglic Acid ≥98% 20mg $30 2021-12-16 Buy
Biorbyt Ltd orb259531 Tiglic Acid 98% 20mg $153 2021-12-16 Buy
Biorbyt Ltd orb259531 Tiglic Acid 98% 1000mg $187 2021-12-16 Buy
Chem-Impex 22605 Tiglicacid,≥98%(Assaybytitration,GC)Hazmat ≥98%(Assaybytitration,GC) 25G $39.6 2021-12-16 Buy

Properties

Melting point :61-64 °C(lit.)
Boiling point :95-96 °C12 mm Hg(lit.)
Density :0.969 g/mL at 25 °C(lit.)
refractive index :nD81 1.4342
FEMA :3599 | 2-METHYL-TRANS-2-BUTENOIC ACID
Flash point :101°C
storage temp. :2-8°C
solubility :Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
pka :pK (25°) 5.02
form :Crystalline Powder and Chunks
color :White to beige
Specific Gravity :0.969
Odor :at 10.00 % in dipropylene glycol. sweet dry spicy woody caramel
Odor Type :spicy
Water Solubility :SOLUBLE IN HOT WATER
JECFA Number :1205
Merck :14,9433
BRN :1236500
InChIKey :UIERETOOQGIECD-ONEGZZNKSA-N
LogP :1.35
CAS DataBase Reference :80-59-1(CAS DataBase Reference)
NIST Chemistry Reference :2-Butenoic acid, 2-methyl-, (E)-(80-59-1)
EPA Substance Registry System :2-Butenoic acid, 2-methyl-, (2E)- (80-59-1)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Tiglic acid (also (E)-2-Methylbut-2-enoic acid) is an organic acid. It occurs in croton oil, Roman chamomile, and geranium. It can be prepared by dehydration of MEK cyanohydrin, followed by the hydrolysis of the nitrile function. It is either in the form of a thick syrup or colorless crystals.  It is with a sweet, warm, spicy odor. It is used to synthesize esters for perfume manufacturing industry and as a raw material to produce acids and esters, which are applied as flavoring agent for food and beverage industry. Tiglic acid is also a useful starting material in the synthesis of pharmaceutical intermediates.

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