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ChemicalBook >> CAS DataBase List >> RockPhos Pd G3

RockPhos Pd G3

RockPhos Pd G3 price.
  • $103 - $4136
  • Product name: RockPhos Pd G3
  • CAS: 2009020-38-4
  • MF: C44H63NO4PPdS-
  • MW: 839.434081
  • EINECS:
  • MDL Number:MFCD27952542
  • Synonyms:METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3-METHOXY-6-METHYL-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ROCKPHOSPALLADACYCLEGEN.3];Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-t-butylphosphino)-3-methoxy-6-methyl-2’,4’,6’-tri-i-propylbiphenyl](2’-amino-2-biphenylyl)palladium(II);2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium;Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (RockPhos Pd G3);RockPhos Pd G3;Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II);2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium
8 prices
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Brand
  • Arctom
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 100MG
  • 250mg
  • 500MG
  • 2g
  • 5G
  • 10g
  • ManufacturerArctom
  • Product numberSY247323
  • Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3-methoxy-6-methyl-2’,4’,6’-tri-i-propylbiphenyl](2’-amino-2-biphenylyl)palladium(II)
  • Packaging250mg
  • Price$830
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number773905
  • Product descriptionRockPhos Pd G3
  • Packaging5G
  • Price$3950
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number773905
  • Product descriptionRockPhos Pd G3
  • Packaging500MG
  • Price$532
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number773905
  • Product descriptionRockPhos Pd G3
  • Packaging100MG
  • Price$112
  • Updated2023-06-20
  • Buy
  • ManufacturerStrem Chemicals
  • Product number46-0335
  • Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]
  • Packaging100mg
  • Price$103
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number46-0335
  • Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]
  • Packaging500mg
  • Price$426
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number46-0335
  • Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]
  • Packaging2g
  • Price$1274
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number46-0335
  • Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]
  • Packaging10g
  • Price$4136
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Arctom SY247323 Methanesulfonato[2-(di-t-butylphosphino)-3-methoxy-6-methyl-2’,4’,6’-tri-i-propylbiphenyl](2’-amino-2-biphenylyl)palladium(II) 250mg $830 2021-12-16 Buy
Sigma-Aldrich 773905 RockPhos Pd G3 5G $3950 2023-06-20 Buy
Sigma-Aldrich 773905 RockPhos Pd G3 500MG $532 2023-06-20 Buy
Sigma-Aldrich 773905 RockPhos Pd G3 100MG $112 2023-06-20 Buy
Strem Chemicals 46-0335 Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3] 100mg $103 2024-03-01 Buy
Strem Chemicals 46-0335 Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3] 500mg $426 2024-03-01 Buy
Strem Chemicals 46-0335 Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3] 2g $1274 2024-03-01 Buy
Strem Chemicals 46-0335 Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3] 10g $4136 2024-03-01 Buy

Properties

Melting point :220-250 °C
form :Powder
color :brown
InChIKey :QAHMIRGGAFFMDS-UHFFFAOYSA-N
CAS DataBase Reference :2009020-38-4

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P337+P313 IF eye irritation persists: Get medical advice/attention.

Description

Buchwald 3rd Generation Pd Precatalyst containing bulk RockPhos ligand. This system has been shown to be effective for cross-coupling reactions like the arylation of aliphatic alcohols.


Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands

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