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ChemicalBook >> CAS DataBase List >> Boc-D-Phenylglycine

Boc-D-Phenylglycine

Boc-D-Phenylglycine price.
  • $11.2 - $1680
  • Product name: Boc-D-Phenylglycine
  • CAS: 33125-05-2
  • MF: C13H17NO4
  • MW: 251.28
  • EINECS:1533716-785-6
  • MDL Number:MFCD00062043
  • Synonyms:Boc-(R)-2-aminobenzeneacetic acid;N-(tert-Butoxycarbonyl)-D-2-phenylglycine;N-Boc-D-2-phenylglycine;N-(tert-butoxycarbonyl)-D-alpha-phenylglycine;N-Boc-D-2-phenylglycine Boc-D-Phg-OH;N-Boc-D-phenylglycine (Boc-D-Phg-OH);BOC-(PHENYL)GLY-OH;BOC-L-PHG
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  • Acrotein
  • Activate Scientific
  • AK Scientific
  • Alfa Aesar
  • American Custom Chemicals Corporation
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  • 1g
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  • 1kg
  • ManufacturerAcrotein
  • Product numberA-3461
  • Product descriptionBoc-D-phenylglycine 97%
  • Packaging25g
  • Price$28.23
  • Updated2021-12-16
  • Buy
  • ManufacturerAcrotein
  • Product numberA-3461
  • Product descriptionBoc-D-phenylglycine 97%
  • Packaging1kg
  • Price$403.33
  • Updated2021-12-16
  • Buy
  • ManufacturerActivate Scientific
  • Product numberAS91730
  • Product description(R)-2-(Boc-amino)-2-phenylacetic Acid 98+% ee
  • Packaging25g
  • Price$58
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ91433
  • Product descriptionN-Boc-D-Phenylglycine
  • Packaging25g
  • Price$38
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL18540
  • Product descriptionN-Boc-D-phenylglycine, 99%
  • Packaging1g
  • Price$41.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL18540
  • Product descriptionN-Boc-D-phenylglycine, 99%
  • Packaging5g
  • Price$129.65
  • Updated2024-03-01
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberAAA0035189
  • Product description(R)-2-(TERT-BUTOXYCARBONYLAMINO)-2-PHENYLACETIC ACID 95.00%
  • Packaging1G
  • Price$721.57
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberAAA0035189
  • Product description(R)-2-(TERT-BUTOXYCARBONYLAMINO)-2-PHENYLACETIC ACID 95.00%
  • Packaging2.5G
  • Price$983.88
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberAAA0035189
  • Product description(R)-2-(TERT-BUTOXYCARBONYLAMINO)-2-PHENYLACETIC ACID 95.00%
  • Packaging5G
  • Price$1168.42
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberAAA0035189
  • Product description(R)-2-(TERT-BUTOXYCARBONYLAMINO)-2-PHENYLACETIC ACID 95.00%
  • Packaging50G
  • Price$1680
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR480572
  • Product descriptionBoc-D-alpha-Phenylglycine 98%
  • Packaging100g
  • Price$221
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFB39266
  • Product descriptionN-Boc-D-phenylglycine
  • Packaging250g
  • Price$62.5
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFB39266
  • Product descriptionN-Boc-D-phenylglycine
  • Packaging500g
  • Price$100
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFB39266
  • Product descriptionN-Boc-D-phenylglycine
  • Packaging1kg
  • Price$162.5
  • Updated2021-12-16
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  • ManufacturerChemenu
  • Product numberCM252268
  • Product descriptionBoc-D-Phg-OH 98%
  • Packaging100g
  • Price$111
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number03535
  • Product descriptionBoc-D-phenylglycine,99%(HPLC) 99%(HPLC)
  • Packaging1KG
  • Price$761.6
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein A-3461 Boc-D-phenylglycine 97% 25g $28.23 2021-12-16 Buy
Acrotein A-3461 Boc-D-phenylglycine 97% 1kg $403.33 2021-12-16 Buy
Activate Scientific AS91730 (R)-2-(Boc-amino)-2-phenylacetic Acid 98+% ee 25g $58 2021-12-16 Buy
AK Scientific J91433 N-Boc-D-Phenylglycine 25g $38 2021-12-16 Buy
Alfa Aesar L18540 N-Boc-D-phenylglycine, 99% 1g $41.65 2024-03-01 Buy
Alfa Aesar L18540 N-Boc-D-phenylglycine, 99% 5g $129.65 2024-03-01 Buy
American Custom Chemicals Corporation AAA0035189 (R)-2-(TERT-BUTOXYCARBONYLAMINO)-2-PHENYLACETIC ACID 95.00% 1G $721.57 2021-12-16 Buy
American Custom Chemicals Corporation AAA0035189 (R)-2-(TERT-BUTOXYCARBONYLAMINO)-2-PHENYLACETIC ACID 95.00% 2.5G $983.88 2021-12-16 Buy
American Custom Chemicals Corporation AAA0035189 (R)-2-(TERT-BUTOXYCARBONYLAMINO)-2-PHENYLACETIC ACID 95.00% 5G $1168.42 2021-12-16 Buy
American Custom Chemicals Corporation AAA0035189 (R)-2-(TERT-BUTOXYCARBONYLAMINO)-2-PHENYLACETIC ACID 95.00% 50G $1680 2021-12-16 Buy
Apolloscientific OR480572 Boc-D-alpha-Phenylglycine 98% 100g $221 2021-12-16 Buy
Biosynth Carbosynth FB39266 N-Boc-D-phenylglycine 250g $62.5 2021-12-16 Buy
Biosynth Carbosynth FB39266 N-Boc-D-phenylglycine 500g $100 2021-12-16 Buy
Biosynth Carbosynth FB39266 N-Boc-D-phenylglycine 1kg $162.5 2021-12-16 Buy
Chemenu CM252268 Boc-D-Phg-OH 98% 100g $111 2021-12-16 Buy
Chem-Impex 03535 Boc-D-phenylglycine,99%(HPLC) 99%(HPLC) 1KG $761.6 2021-12-16 Buy

Properties

Melting point :88-91 °C
alpha :-142 º (c=1% in ethanol)
Boiling point :407.2±38.0 °C(Predicted)
Density :1.182±0.06 g/cm3(Predicted)
refractive index :-140 ° (C=1, EtOH)
storage temp. :Keep in dark place,Sealed in dry,Room Temperature
solubility :DMSO, Methanol
pka :3.51±0.10(Predicted)
form :Crystalline Powder
color :White
optical activity :[α]20/D 141.0±5.0°, c = 1% in ethanol
Water Solubility :Insoluble in water. Slightly soluble in DMSO and methanol.
BRN :3033982
CAS DataBase Reference :33125-05-2(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word:
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Description

It is a reagent of choice for assignment of absolute configuration of chiral primary amines by 1H NMR, giving better results than Mosher's acid ((R)-(+)-?-Methoxy-?-(trifluoromethyl)-phenyl-acetic acid. αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.

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