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ChemicalBook >> CAS DataBase List >> (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE price.
  • $27.48 - $1180
  • Product name: (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
  • CAS: 64536-78-3
  • MF: C31H47F6IrNP2
  • MW: 801.88
  • EINECS:
  • MDL Number:MFCD00075097
  • Synonyms:(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTA- DIENE)(PYRIDINE)IRIDIUM(I) PF6;(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,99%;(1,5-Cyclooctadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate;(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I)hexafluorophosphate,99%CRABTREE'SCATALYST;1,5-Cyclooctadiene-(pyridyl)-(tricyclohexylphosphine)-iridium hexafluoropho;(cycloocta-1,5-diene)pyridyl(tricyclohexyl-phosphine)iridium(I)hexafluorophosphate Crabtree's catalyst;
    (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluoro phosphate;Hexafluorophosphate (tricyclohexyl phosphine) (1,5-cyclooctadiene) (pyridine) iridium
35 prices
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Brand
  • AK Scientific
  • Alfa Aesar
  • Ambeed
  • American Custom Chemicals Corporation
  • Arctom
  • Ark Pharm
  • Biosynth Carbosynth
  • Chem-Impex
  • ChemSupplyAustralia
  • Crysdot
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 50mg
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  • ManufacturerAK Scientific
  • Product numberY1560
  • Product descriptionCrabtree'scatalyst
  • Packaging250mg
  • Price$136
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042057
  • Product description1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%
  • Packaging50mg
  • Price$50.6
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042057
  • Product description1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%
  • Packaging250mg
  • Price$189
  • Updated2023-06-20
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233161
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 99+%
  • Packaging100mg
  • Price$28
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233161
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 99+%
  • Packaging250mg
  • Price$56
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233161
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 99+%
  • Packaging1g
  • Price$142
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233161
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 99+%
  • Packaging5g
  • Price$698
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233161
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 99+%
  • Packaging10g
  • Price$1180
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOPC0000983
  • Product descriptionCRABTREE'S CATALYST 95.00%
  • Packaging50MG
  • Price$249.27
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOPC0000983
  • Product descriptionCRABTREE'S CATALYST 95.00%
  • Packaging250MG
  • Price$717.34
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS443662
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 97%
  • Packaging100mg
  • Price$28
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS710539
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate ≥99%
  • Packaging100mg
  • Price$30
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS443662
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 97%
  • Packaging250mg
  • Price$53
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS710539
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate ≥99%
  • Packaging250mg
  • Price$55
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS443662
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 97%
  • Packaging1g
  • Price$141
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS710539
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate ≥99%
  • Packaging1g
  • Price$174
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific Y1560 Crabtree'scatalyst 250mg $136 2021-12-16 Buy
Alfa Aesar 042057 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99% 50mg $50.6 2023-06-20 Buy
Alfa Aesar 042057 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99% 250mg $189 2023-06-20 Buy
Ambeed A1233161 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 99+% 100mg $28 2021-12-16 Buy
Ambeed A1233161 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 99+% 250mg $56 2021-12-16 Buy
Ambeed A1233161 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 99+% 1g $142 2021-12-16 Buy
Ambeed A1233161 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 99+% 5g $698 2021-12-16 Buy
Ambeed A1233161 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 99+% 10g $1180 2021-12-16 Buy
American Custom Chemicals Corporation OPC0000983 CRABTREE'S CATALYST 95.00% 50MG $249.27 2021-12-16 Buy
American Custom Chemicals Corporation OPC0000983 CRABTREE'S CATALYST 95.00% 250MG $717.34 2021-12-16 Buy
Arctom AS443662 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 97% 100mg $28 2021-12-16 Buy
Arctom AS710539 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate ≥99% 100mg $30 2021-12-16 Buy
Arctom AS443662 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 97% 250mg $53 2021-12-16 Buy
Arctom AS710539 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate ≥99% 250mg $55 2021-12-16 Buy
Arctom AS443662 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 97% 1g $141 2021-12-16 Buy
Arctom AS710539 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate ≥99% 1g $174 2021-12-16 Buy

Properties

Melting point :175 °C (dec.)(lit.)
Density :1.67 g/cm3
storage temp. :Inert atmosphere,Room Temperature
solubility :Chloroform (Slightly)
form :Crystalline Powder
color :Orange
Water Solubility :Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water.
Sensitive :Moisture Sensitive
Merck :13,2594

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

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