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ChemicalBook >> CAS DataBase List >> Sodium bis(2-methoxyethoxy)aluminiumhydride

Sodium bis(2-methoxyethoxy)aluminiumhydride

Sodium bis(2-methoxyethoxy)aluminiumhydride price.
  • $22 - $410
  • Product name: Sodium bis(2-methoxyethoxy)aluminiumhydride
  • CAS: 22722-98-1
  • MF: C6H16AlNaO4
  • MW: 202.16
  • EINECS:245-178-2
  • MDL Number:MFCD00011631
  • Synonyms:DIHYDROBIS-(2-METHOXYETHOXY)-ALUMINATE SODIUM;VITRIDE(R);VITRIDE(TM);Aluminate(1-),dihydrobis(2-methoxyethanolato-O,O’)-,sodium ;dihydrobis(2-methoxyethanolato-o,o’)-aluminate(1-sodium ;SODIUM BIS(2-METHOXYETHOXY)ALUMINUM HYDRIDE: 70% W/W IN TOLUENE;Sodium dihydrobis(2-methoxyethoxy)aluminate, 70% w/w in toluene;Sodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca. 3.6mol/L)
16 prices
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Brand
  • AHH
  • Alfa Aesar
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 250mg
  • 25g
  • 50g
  • 100g
  • 250g
  • 500g
  • 1000g
  • 1Kg
  • 2.5Kg
  • 5000g
  • ManufacturerAHH
  • Product numberMT-22287
  • Product descriptionSodiumbis(2-methoxyethoxy)aluminiumhydride 98%
  • Packaging5000g
  • Price$410
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13292
  • Product descriptionSodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene.
  • Packaging1000g
  • Price$219
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13292
  • Product descriptionSodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene.
  • Packaging250g
  • Price$67.3
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13292
  • Product descriptionSodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene.
  • Packaging50g
  • Price$37.9
  • Updated2024-03-01
  • Buy
  • ManufacturerOakwood
  • Product number099606
  • Product descriptionSodium bis(2-methoxyethoxy)aluminum hydride 70% w/w in toluene
  • Packaging25g
  • Price$22
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number099606
  • Product descriptionSodium bis(2-methoxyethoxy)aluminum hydride 70% w/w in toluene
  • Packaging100g
  • Price$33
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number099606
  • Product descriptionSodium bis(2-methoxyethoxy)aluminum hydride 70% w/w in toluene
  • Packaging1Kg
  • Price$99
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number099606
  • Product descriptionSodium bis(2-methoxyethoxy)aluminum hydride 70% w/w in toluene
  • Packaging2.5Kg
  • Price$214
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number196193
  • Product descriptionRed-Al? sodium bis(2-methoxyethoxy)aluminum hydride solution ≥60 wt. % in toluene
  • Packaging500g
  • Price$129
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number196193
  • Product descriptionRed-Al? sodium bis(2-methoxyethoxy)aluminum hydride solution ≥60 wt. % in toluene
  • Packaging50g
  • Price$50.2
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number93-1077
  • Product descriptionSodium dihydrobis(2-methoxyethoxy)aluminate, 70% in toluene
  • Packaging100g
  • Price$43
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number93-1077
  • Product descriptionSodium dihydrobis(2-methoxyethoxy)aluminate, 70% in toluene
  • Packaging500g
  • Price$107
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberS0467
  • Product descriptionSodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca. 3.6mol/L)
  • Packaging25g
  • Price$39
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberS0467
  • Product descriptionSodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca. 3.6mol/L)
  • Packaging100g
  • Price$63
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberS0467
  • Product descriptionSodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca. 3.6mol/L)
  • Packaging500g
  • Price$141
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberS667078
  • Product descriptionSodiumBis(2-methoxyethoxy)aluminiumhydride(60%intoluene)
  • Packaging250mg
  • Price$45
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-22287 Sodiumbis(2-methoxyethoxy)aluminiumhydride 98% 5000g $410 2021-12-16 Buy
Alfa Aesar A13292 Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene. 1000g $219 2024-03-01 Buy
Alfa Aesar A13292 Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene. 250g $67.3 2024-03-01 Buy
Alfa Aesar A13292 Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene. 50g $37.9 2024-03-01 Buy
Oakwood 099606 Sodium bis(2-methoxyethoxy)aluminum hydride 70% w/w in toluene 25g $22 2021-12-16 Buy
Oakwood 099606 Sodium bis(2-methoxyethoxy)aluminum hydride 70% w/w in toluene 100g $33 2021-12-16 Buy
Oakwood 099606 Sodium bis(2-methoxyethoxy)aluminum hydride 70% w/w in toluene 1Kg $99 2021-12-16 Buy
Oakwood 099606 Sodium bis(2-methoxyethoxy)aluminum hydride 70% w/w in toluene 2.5Kg $214 2021-12-16 Buy
Sigma-Aldrich 196193 Red-Al? sodium bis(2-methoxyethoxy)aluminum hydride solution ≥60 wt. % in toluene 500g $129 2024-03-01 Buy
Sigma-Aldrich 196193 Red-Al? sodium bis(2-methoxyethoxy)aluminum hydride solution ≥60 wt. % in toluene 50g $50.2 2024-03-01 Buy
Strem Chemicals 93-1077 Sodium dihydrobis(2-methoxyethoxy)aluminate, 70% in toluene 100g $43 2024-03-01 Buy
Strem Chemicals 93-1077 Sodium dihydrobis(2-methoxyethoxy)aluminate, 70% in toluene 500g $107 2024-03-01 Buy
TCI Chemical S0467 Sodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca. 3.6mol/L) 25g $39 2024-03-01 Buy
TCI Chemical S0467 Sodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca. 3.6mol/L) 100g $63 2024-03-01 Buy
TCI Chemical S0467 Sodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca. 3.6mol/L) 500g $141 2024-03-01 Buy
TRC S667078 SodiumBis(2-methoxyethoxy)aluminiumhydride(60%intoluene) 250mg $45 2021-12-16 Buy

Properties

Boiling point :396-402°C
Density :1.036 g/mL at 25 °C
vapor pressure :21 mm Hg ( 20 °C)
Flash point :40 °F
storage temp. :Flammables area
solubility :Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.
form :Viscous Liquid
Specific Gravity :1.036
color :Clear to slightly hazy, colorless to light amber
explosive limit :7%
Water Solubility :reacts
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Merck :14,8564
Exposure limits :ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) InChIKey :OKUDBXZACZBZJE-UHFFFAOYSA-N
LogP :-2.64 at 25℃ and pH7
CAS DataBase Reference :22722-98-1(CAS DataBase Reference)
EPA Substance Registry System :Aluminate(1-), dihydrobis[2-(methoxy-.kappa.O)ethanolato-.kappa.O]-, sodium (22722-98-1)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.

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