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ChemicalBook >> CAS DataBase List >> 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE

2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE

2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE price.
  • $109.65 - $8316
  • Product name: 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE
  • CAS: 21450-64-6
  • MF: C8H9BrMg
  • MW: 209.37
  • EINECS:
  • MDL Number:MFCD00192083
  • Synonyms:2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE;2,6-Dimethylphenylmagnesium bromide solution;2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE, 1.0 M SOLUTION IN TETRAHYDROFURAN;2,6-Dimethylphenylmagnesium bromide solution 1.0 in THF;2,6-DiMethylphenylMagnesiuM broMide, 0.5M in 2-MeTHF;2,6-DiMethylphenylMagnesiuM broMide, 1M solution in THF, AcroSeal;2,6-Dimethylphenylmagnesium bromide solution 1.0 M in THF;2,6-Dimethylphenylmagnesium bromide, 0.5 M in THF
11 prices
Selected condition：
Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Rieke Metals
  • Sigma-Aldrich
Package
  • 50mL
  • 100ml
  • 500ML
  • 800ml
  • 1L
  • ManufacturerAlfa Aesar
  • Product numberH54138
  • Product description2,6-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF
  • Packaging100ml
  • Price$109.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0005851
  • Product description2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 95.00%
  • Packaging100ML
  • Price$2714.25
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0005851
  • Product description2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 95.00%
  • Packaging500ML
  • Price$5313
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0005851
  • Product description2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 95.00%
  • Packaging1L
  • Price$8316
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product number3044
  • Product description2,6-Dimethylphenylmagnesiumbromide
  • Packaging50mL
  • Price$204
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product numberG0212
  • Product description2,6-Dimethylphenylmagnesiumbromide
  • Packaging50mL
  • Price$204
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product number3044
  • Product description2,6-Dimethylphenylmagnesiumbromide
  • Packaging100mL
  • Price$356
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product numberG0212
  • Product description2,6-Dimethylphenylmagnesiumbromide
  • Packaging100mL
  • Price$356
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product number3302
  • Product description2,6-Dimethylphenylmagnesiumbromide
  • Packaging50mL
  • Price$395
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number425508
  • Product description2,6-Dimethylphenylmagnesium bromide solution 1.0 M in THF
  • Packaging800ml
  • Price$735
  • Updated2023-01-07
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number425508
  • Product description2,6-Dimethylphenylmagnesium bromide solution 1.0 M in THF
  • Packaging100ml
  • Price$160
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar H54138 2,6-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF 100ml $109.65 2024-03-01 Buy
American Custom Chemicals Corporation ING0005851 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 95.00% 100ML $2714.25 2021-12-16 Buy
American Custom Chemicals Corporation ING0005851 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 95.00% 500ML $5313 2021-12-16 Buy
American Custom Chemicals Corporation ING0005851 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 95.00% 1L $8316 2021-12-16 Buy
Rieke Metals 3044 2,6-Dimethylphenylmagnesiumbromide 50mL $204 2021-12-16 Buy
Rieke Metals G0212 2,6-Dimethylphenylmagnesiumbromide 50mL $204 2021-12-16 Buy
Rieke Metals 3044 2,6-Dimethylphenylmagnesiumbromide 100mL $356 2021-12-16 Buy
Rieke Metals G0212 2,6-Dimethylphenylmagnesiumbromide 100mL $356 2021-12-16 Buy
Rieke Metals 3302 2,6-Dimethylphenylmagnesiumbromide 50mL $395 2021-12-16 Buy
Sigma-Aldrich 425508 2,6-Dimethylphenylmagnesium bromide solution 1.0 M in THF 800ml $735 2023-01-07 Buy
Sigma-Aldrich 425508 2,6-Dimethylphenylmagnesium bromide solution 1.0 M in THF 100ml $160 2024-03-01 Buy

Properties

Boiling point :65-67 °C
Density :0.998 g/mL at 25 °C
Flash point :−2 °F
form :Solution
color :Colorless to yellow-brown
Sensitive :Air & Moisture Sensitive
CAS DataBase Reference :21450-64-6

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger GHS hazard pictograms P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Description

2,6-Dimethylphenylmagnesium bromide can be used:
  • As an intermediate in the synthesis of dibutyl(5,10-dihydro-1,9-di-p-toluoyl-5-p-tolyldipyrrinato)tin(IV), which is further used in the preparation of zinc-based porphyrin.
  • As a substrate in the preparation of substituted fluorenes by reacting with 2-substituted arenesulfonates and dihaloarenes.

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