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ChemicalBook >> CAS DataBase List >> 2-CHLOROPHENYLZINC IODIDE

2-CHLOROPHENYLZINC IODIDE

2-CHLOROPHENYLZINC IODIDE price.
  • $216 - $5544
  • Product name: 2-CHLOROPHENYLZINC IODIDE
  • CAS: 148651-35-8
  • MF: C6H4ClIZn
  • MW: 303.84
  • EINECS:
  • MDL Number:MFCD01863648
  • Synonyms:2-CHLOROPHENYLZINC IODIDE;2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;2-chlorophenylzinc iodide solution;2-Chlorophenylzinc iodide solution 0.5 in THF;2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles;2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;2-Chlorophenylzinc iodide solution 0.5M in THF;2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran
6 prices
Selected condition：
Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Rieke Metals
  • Sigma-Aldrich
Package
  • 50ml
  • 100ML
  • 250ML
  • ManufacturerAlfa Aesar
  • Product numberH58383
  • Product description2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging50ml
  • Price$216
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0005751
  • Product description2-CHLOROPHENYLZINC IODIDE 95.00%
  • Packaging50ML
  • Price$2760.45
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0005751
  • Product description2-CHLOROPHENYLZINC IODIDE 95.00%
  • Packaging100ML
  • Price$3106.95
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0005751
  • Product description2-CHLOROPHENYLZINC IODIDE 95.00%
  • Packaging250ML
  • Price$5544
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product number2135
  • Product description2-Chlorophenylzinciodide
  • Packaging100mL
  • Price$755
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number499803
  • Product description2-Chlorophenylzinc iodide solution 0.5M in THF
  • Packaging50ml
  • Price$273
  • Updated2023-06-20
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar H58383 2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles 50ml $216 2021-12-16 Buy
American Custom Chemicals Corporation ING0005751 2-CHLOROPHENYLZINC IODIDE 95.00% 50ML $2760.45 2021-12-16 Buy
American Custom Chemicals Corporation ING0005751 2-CHLOROPHENYLZINC IODIDE 95.00% 100ML $3106.95 2021-12-16 Buy
American Custom Chemicals Corporation ING0005751 2-CHLOROPHENYLZINC IODIDE 95.00% 250ML $5544 2021-12-16 Buy
Rieke Metals 2135 2-Chlorophenylzinciodide 100mL $755 2021-12-16 Buy
Sigma-Aldrich 499803 2-Chlorophenylzinc iodide solution 0.5M in THF 50ml $273 2023-06-20 Buy

Properties

Density :0.973 g/mL at 25 °C
Flash point :1 °F
storage temp. :2-8°C
Sensitive :Air & Light Sensitive
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) CAS DataBase Reference :148651-35-8

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Description

2-Chlorophenylzinc iodide is an organozinc compound, which can be used as a reactant in Negishi cross-coupling reaction to construct carbon-carbon bonds by reacting with organic halides using nickel or palladium catalysts.
It can also be utilized as a reactant to prepare:
  • Arylmethanes via rhodium-catalyzed cross-coupling reaction with methyl halides.
  • (2-chlorobenzyl)trimethylsilane by Rh-catalyzed cross-coupling reaction with (iodomethyl)trimethylsilane.
  • Dichloro biphenyl by palladium catalyzed oxidative homocoupling reaction using N-chlorosuccinimide (NCS) or O2 as the oxidant.

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