| Identification | Back Directory | [Name]
2-CHLOROPHENYLZINC IODIDE | [CAS]
148651-35-8 | [Synonyms]
2-CHLOROPHENYLZINC IODIDE
2-chlorophenylzinc iodide solution
2-Chlorophenylzinc iodide solution 0.5 in THF
2-Chlorophenylzinc iodide solution 0.5M in THF
2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran
2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles
2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles | [Molecular Formula]
C6H4ClIZn | [MDL Number]
MFCD01863648 | [MOL File]
148651-35-8.mol | [Molecular Weight]
303.84 |
| Chemical Properties | Back Directory | [density ]
0.973 g/mL at 25 °C
| [Fp ]
1 °F
| [storage temp. ]
2-8°C | [Sensitive ]
Air & Light Sensitive | [Exposure limits]
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) | [CAS DataBase Reference]
148651-35-8 |
| Hazard Information | Back Directory | [Uses]
2-Chlorophenylzinc iodide is an organozinc compound, which can be used as a reactant in Negishi cross-coupling reaction to construct carbon-carbon bonds by reacting with organic halides using nickel or palladium catalysts.
It can also be utilized as a reactant to prepare:
- Arylmethanes via rhodium-catalyzed cross-coupling reaction with methyl halides.
- (2-chlorobenzyl)trimethylsilane by Rh-catalyzed cross-coupling reaction with (iodomethyl)trimethylsilane.
- Dichloro biphenyl by palladium catalyzed oxidative homocoupling reaction using N-chlorosuccinimide (NCS) or O2 as the oxidant.
|
|
| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Infinity SCI
|
| Tel: |
400-400-1062016 17800804092 |
| Website: |
http://www.infsci.com |
| Company Name: |
Energy Chemical
|
| Tel: |
021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
SIGMA-RBI
|
| Tel: |
800 736 3690 (Orders) |
| Website: |
www.sigma-aldrich.com |
|