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ChemicalBook >> CAS DataBase List >> Borane-tetrahydrofuran complex

Borane-tetrahydrofuran complex

Borane-tetrahydrofuran complex price.
  • $28.5 - $1050
  • Product name: Borane-tetrahydrofuran complex
  • CAS: 14044-65-6
  • MF: C4H11BO
  • MW: 85.94
  • EINECS:237-881-8
  • MDL Number:MFCD00012429
  • Synonyms:borane-tetrahydrofurancomplex,bthf-1m ;BORAN-TETRAHYDROFURANCOMPLEX;BORANE-TETRAHYDROFURANCOMPLEX,1MSOLUTIONINTETRAHYDROFURAN;Borane tetrahydrofuran complex 1.0 molar in THF;Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4;Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca. 0.9mol/L) (stabilized with Sodium Borohydride);Borane dimethyl sulfide complex, 2M in tetrahydrofuran, packaged under Argon in resealable ChemSeal bottles;Borane, 1M in tetrahydrofuran, packaged under Argon in resealable ChemSeal bottles
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Brand
  • Alfa Aesar
  • Biosynth Carbosynth
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
  • SynQuest Laboratories
  • TCI Chemical
  • TRC
  • Usbiological
Package
  • 25g
  • 25ml
  • 50ml
  • 90g
  • 100ml
  • 4x25ml
  • 100g
  • 180g
  • 200ml
  • 500ml
  • 500g
  • 720g
  • 800ml
  • 1440g
  • 3kg
  • ManufacturerAlfa Aesar
  • Product numberL13961
  • Product descriptionBorane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4
  • Packaging25ml
  • Price$28.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number043291
  • Product descriptionBorane-tetrahydrofuran complex, 1M soln. in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging100ml
  • Price$78.9
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL13961
  • Product descriptionBorane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4
  • Packaging100ml
  • Price$78.9
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number043291
  • Product descriptionBorane-tetrahydrofuran complex, 1M soln. in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging500ml
  • Price$223
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL13961
  • Product descriptionBorane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4
  • Packaging500ml
  • Price$223
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB46350
  • Product descriptionBorane-tetrahydrofuran complex - 1.0M in THF
  • Packaging90g
  • Price$72
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFB46350
  • Product descriptionBorane-tetrahydrofuran complex - 1.0M in THF
  • Packaging180g
  • Price$126
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFB46350
  • Product descriptionBorane-tetrahydrofuran complex - 1.0M in THF
  • Packaging720g
  • Price$360
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFB46350
  • Product descriptionBorane-tetrahydrofuran complex - 1.0M in THF
  • Packaging1440g
  • Price$648
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFB46350
  • Product descriptionBorane-tetrahydrofuran complex - 1.0M in THF
  • Packaging3kg
  • Price$1050
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number044988
  • Product descriptionBorane-tetrahydrofurancomplex,BTHF-1MinTHFcontains0.005Msodiumborohydrideasstabilizer
  • Packaging800ml
  • Price$175
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number044988
  • Product descriptionBorane-tetrahydrofurancomplex,BTHF-1MinTHFcontains0.005Msodiumborohydrideasstabilizer
  • Packaging200ml
  • Price$60
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number044988
  • Product descriptionBorane-tetrahydrofurancomplex,BTHF-1MinTHFcontains0.005Msodiumborohydrideasstabilizer
  • Packaging100ml
  • Price$40
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number650412
  • Product descriptionBorane tetrahydrofuran complex solution 1.0M in THF, contains 0.005M
  • Packaging4x25ml
  • Price$42.6
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number650412
  • Product descriptionBorane tetrahydrofuran complex solution 1.0M in THF, contains 0.005M
  • Packaging100ml
  • Price$44.7
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number176192
  • Product descriptionBorane tetrahydrofuran complex solution 1.0 M in THF
  • Packaging4x25ml
  • Price$60.8
  • Updated2024-03-01
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Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar L13961 Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4 25ml $28.5 2021-12-16 Buy
Alfa Aesar 043291 Borane-tetrahydrofuran complex, 1M soln. in THF, packaged under Argon in resealable ChemSeal? bottles 100ml $78.9 2021-12-16 Buy
Alfa Aesar L13961 Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4 100ml $78.9 2021-12-16 Buy
Alfa Aesar 043291 Borane-tetrahydrofuran complex, 1M soln. in THF, packaged under Argon in resealable ChemSeal? bottles 500ml $223 2021-12-16 Buy
Alfa Aesar L13961 Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4 500ml $223 2021-12-16 Buy
Biosynth Carbosynth FB46350 Borane-tetrahydrofuran complex - 1.0M in THF 90g $72 2021-12-16 Buy
Biosynth Carbosynth FB46350 Borane-tetrahydrofuran complex - 1.0M in THF 180g $126 2021-12-16 Buy
Biosynth Carbosynth FB46350 Borane-tetrahydrofuran complex - 1.0M in THF 720g $360 2021-12-16 Buy
Biosynth Carbosynth FB46350 Borane-tetrahydrofuran complex - 1.0M in THF 1440g $648 2021-12-16 Buy
Biosynth Carbosynth FB46350 Borane-tetrahydrofuran complex - 1.0M in THF 3kg $1050 2021-12-16 Buy
Oakwood 044988 Borane-tetrahydrofurancomplex,BTHF-1MinTHFcontains0.005Msodiumborohydrideasstabilizer 800ml $175 2021-12-16 Buy
Oakwood 044988 Borane-tetrahydrofurancomplex,BTHF-1MinTHFcontains0.005Msodiumborohydrideasstabilizer 200ml $60 2021-12-16 Buy
Oakwood 044988 Borane-tetrahydrofurancomplex,BTHF-1MinTHFcontains0.005Msodiumborohydrideasstabilizer 100ml $40 2021-12-16 Buy
Sigma-Aldrich 650412 Borane tetrahydrofuran complex solution 1.0M in THF, contains 0.005M 4x25ml $42.6 2024-03-01 Buy
Sigma-Aldrich 650412 Borane tetrahydrofuran complex solution 1.0M in THF, contains 0.005M 100ml $44.7 2024-03-01 Buy
Sigma-Aldrich 176192 Borane tetrahydrofuran complex solution 1.0 M in THF 4x25ml $60.8 2024-03-01 Buy

Properties

Melting point :-17 °C
Boiling point :35 °C
Density :0.898 g/mL at 25 °C
Flash point :1 °F
storage temp. :Store at <= 20°C.
form :Liquid
color :Colorless
Water Solubility :REACTS
Sensitive :Air & Moisture Sensitive
BRN :3668402
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) Stability :Stable, but may form explosive peroxides in contact with air. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents, alcohols. Reacts violently with water. Highly flammable. Store under inert gas.
CAS DataBase Reference :14044-65-6(CAS DataBase Reference)
EPA Substance Registry System :Boron, trihydro(tetrahydrofuran)-, (T-4)- (14044-65-6)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Description

Borane-tetrahydrofuran complex is an important reagent used in the reduction of certain functional groups viz. aldehyde, ketone, carboxylic acid, amide, oxime, imine and nitrile. It is also used as hydro borating agent. It acts as a borane source for oxazaborolidine catalyzed asymmetric reductions. It is utilized to reduce nylon surface amide groups to secondary amines.

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