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ChemicalBook >> CAS DataBase List >> DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) price.
  • $27 - $755
  • Product name: DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
  • CAS: 134524-84-8
  • MF: C44H32Cl2P2Ru
  • MW: 794.65
  • EINECS:634-379-4
  • MDL Number:MFCD01073794
  • Synonyms:(S)-(-)-2,2''-Bis-(diphenylphosphino)-1,1''-binaphthyl ruthenium dichloride;[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride;Dichloro〔(S)-(－)-2,2-bis(diphenylphosphino)-1,1-binaphthyl〕ruthenium(Ⅱ);Dichloro[(S)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(S)-BINAP]RuCl2;(S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium;-binaphthyl]dichlororuthenium;-binaphthyl]ruthenium(II),(S-BINAP)RuCl2;Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
18 prices
Selected condition：
Brand
  • AK Scientific
  • Alichem
  • Ambeed
  • Chemenu
  • Crysdot
  • Labseeker
  • Matrix Scientific
  • Medical Isotopes, Inc.
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • 2g
  • 5g
  • ManufacturerAK Scientific
  • Product number6212AA
  • Product descriptionDichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1-binaphthyl]ruthenium(II)
  • Packaging1g
  • Price$150
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number134524848
  • Product descriptionDichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • Packaging1g
  • Price$182.36
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number134524848
  • Product descriptionDichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • Packaging5g
  • Price$591.15
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA833984
  • Product descriptionDichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98%
  • Packaging250mg
  • Price$27
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA833984
  • Product descriptionDichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98%
  • Packaging1g
  • Price$67
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA833984
  • Product descriptionDichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98%
  • Packaging5g
  • Price$201
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM102911
  • Product descriptionDichloro[(S)-2,2''-bis(diphenylphosphino)-1,1''-binaphthyl]ruthenium(II) 98%
  • Packaging1g
  • Price$271
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD52001321
  • Product descriptionDichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98%
  • Packaging5g
  • Price$557
  • Updated2021-12-16
  • Buy
  • ManufacturerLabseeker
  • Product numberSC-67668
  • Product descriptionDICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) 98
  • Packaging5g
  • Price$539
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number098650
  • Product descriptionDichloro [(S)-(-)-2,2'-bis(diphenylphosphino)-1,1-binaphthyl]ruthenium(II) 95+%
  • Packaging250mg
  • Price$189
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number098650
  • Product descriptionDichloro [(S)-(-)-2,2'-bis(diphenylphosphino)-1,1-binaphthyl]ruthenium(II) 95+%
  • Packaging1g
  • Price$420
  • Updated2021-12-16
  • Buy
  • ManufacturerMedical Isotopes, Inc.
  • Product number49871
  • Product description[(S)-2,2??-Bis(diphenylphosphino)-1,1??-binaphthyl]dichlororuthenium
  • Packaging250mg
  • Price$585
  • Updated2021-12-16
  • Buy
  • ManufacturerMedical Isotopes, Inc.
  • Product number49871
  • Product description[(S)-2,2??-Bis(diphenylphosphino)-1,1??-binaphthyl]dichlororuthenium
  • Packaging1g
  • Price$755
  • Updated2021-12-16
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0249
  • Product descriptionDichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
  • Packaging100mg
  • Price$73
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0249
  • Product descriptionDichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
  • Packaging500mg
  • Price$163
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0249
  • Product descriptionDichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
  • Packaging2g
  • Price$486
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 6212AA Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1-binaphthyl]ruthenium(II) 1g $150 2021-12-16 Buy
Alichem 134524848 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 1g $182.36 2021-12-16 Buy
Alichem 134524848 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 5g $591.15 2021-12-16 Buy
Ambeed A833984 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98% 250mg $27 2021-12-16 Buy
Ambeed A833984 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98% 1g $67 2021-12-16 Buy
Ambeed A833984 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98% 5g $201 2021-12-16 Buy
Chemenu CM102911 Dichloro[(S)-2,2''-bis(diphenylphosphino)-1,1''-binaphthyl]ruthenium(II) 98% 1g $271 2021-12-16 Buy
Crysdot CD52001321 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98% 5g $557 2021-12-16 Buy
Labseeker SC-67668 DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) 98 5g $539 2021-12-16 Buy
Matrix Scientific 098650 Dichloro [(S)-(-)-2,2'-bis(diphenylphosphino)-1,1-binaphthyl]ruthenium(II) 95+% 250mg $189 2021-12-16 Buy
Matrix Scientific 098650 Dichloro [(S)-(-)-2,2'-bis(diphenylphosphino)-1,1-binaphthyl]ruthenium(II) 95+% 1g $420 2021-12-16 Buy
Medical Isotopes, Inc. 49871 [(S)-2,2??-Bis(diphenylphosphino)-1,1??-binaphthyl]dichlororuthenium 250mg $585 2021-12-16 Buy
Medical Isotopes, Inc. 49871 [(S)-2,2??-Bis(diphenylphosphino)-1,1??-binaphthyl]dichlororuthenium 1g $755 2021-12-16 Buy
Strem Chemicals 44-0249 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% 100mg $73 2024-03-01 Buy
Strem Chemicals 44-0249 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% 500mg $163 2024-03-01 Buy
Strem Chemicals 44-0249 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% 2g $486 2024-03-01 Buy

Properties

Melting point :>300 ºC
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
solubility :Benzene (Slightly, Heated), Dichloromethane (Slightly, Heated)
form :Powder
color :orange
Sensitive :air sensitive
Stability :Air Sensitive, Moisture Sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

[(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters.

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