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ChemicalBook >> CAS DataBase List >> 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,  price.
  • $19 - $8600
  • Product name: 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
  • CAS: 95408-45-0
  • MF: C26H38Cl2FeP2Pd
  • MW: 645.7
  • EINECS:664-483-5
  • MDL Number:MFCD08064219
  • Synonyms:1,1'-Bis (di-t-butylphosphino);Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladiuM(II), Pd 16.3%;PdCl2(dtbpf), 15% Pd, Product of UMicore;[1,1'-Bis(di-tert-butylphosphino)ferrocene]dichlor;1,1′-Bis-(di-tert.-butylphosphino-)ferrocen-palladiumdichlorid;[1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II)Dichloride,98%;1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, ;Dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II),99%
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  • ManufacturerAcrotein
  • Product numberAS00034
  • Product descriptionPd(dtbpf)Cl2 97%
  • Packaging25g
  • Price$770
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product number6426AC
  • Product description[1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)
  • Packaging1g
  • Price$107
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ94263
  • Product description[1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)
  • Packaging25g
  • Price$1280
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number044829
  • Product descriptionDichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3%
  • Packaging0.1g
  • Price$86.5
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number044829
  • Product descriptionDichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3%
  • Packaging0.25g
  • Price$126
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number044829
  • Product descriptionDichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3%
  • Packaging1g
  • Price$443
  • Updated2023-06-20
  • Buy
  • ManufacturerAlichem
  • Product number95408450
  • Product description1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride
  • Packaging10g
  • Price$402.78
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number95408450
  • Product description1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride
  • Packaging25g
  • Price$898.8
  • Updated2021-12-16
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  • ManufacturerAlichem
  • Product number95408450
  • Product description1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride
  • Packaging100g
  • Price$2935.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA364750
  • Product description1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 98%
  • Packaging250mg
  • Price$19
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA364750
  • Product description1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 98%
  • Packaging1g
  • Price$45
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA364750
  • Product description1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 98%
  • Packaging5g
  • Price$213
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA364750
  • Product description1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 98%
  • Packaging10g
  • Price$376
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA364750
  • Product description1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 98%
  • Packaging25g
  • Price$885
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0003744
  • Product description1,1' BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE PALLADIUM (II) DICHLORIDE 95.00%
  • Packaging5G
  • Price$1631.03
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0003744
  • Product description1,1' BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE PALLADIUM (II) DICHLORIDE 95.00%
  • Packaging1G
  • Price$871.72
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AS00034 Pd(dtbpf)Cl2 97% 25g $770 2021-12-16 Buy
AK Scientific 6426AC [1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 1g $107 2021-12-16 Buy
AK Scientific J94263 [1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 25g $1280 2021-12-16 Buy
Alfa Aesar 044829 Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3% 0.1g $86.5 2023-06-20 Buy
Alfa Aesar 044829 Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3% 0.25g $126 2023-06-20 Buy
Alfa Aesar 044829 Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3% 1g $443 2023-06-20 Buy
Alichem 95408450 1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 10g $402.78 2021-12-16 Buy
Alichem 95408450 1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 25g $898.8 2021-12-16 Buy
Alichem 95408450 1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 100g $2935.5 2021-12-16 Buy
Ambeed A364750 1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 98% 250mg $19 2021-12-16 Buy
Ambeed A364750 1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 98% 1g $45 2021-12-16 Buy
Ambeed A364750 1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 98% 5g $213 2021-12-16 Buy
Ambeed A364750 1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 98% 10g $376 2021-12-16 Buy
Ambeed A364750 1,1'-Bis(di-tert-butylphosphino)ferrocene-palladiumdichloride 98% 25g $885 2021-12-16 Buy
American Custom Chemicals Corporation OGM0003744 1,1' BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE PALLADIUM (II) DICHLORIDE 95.00% 5G $1631.03 2021-12-16 Buy
American Custom Chemicals Corporation OGM0003744 1,1' BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE PALLADIUM (II) DICHLORIDE 95.00% 1G $871.72 2021-12-16 Buy

Properties

Melting point :203-208 °C
storage temp. :-20°C
solubility :Soluble in dichloromethane and chloroform. Partially soluble in acetone, alcohols, tertrahydrofuran and dioxane.
form :crystal
color :dark purple
InChI :InChI=1S/2C13H19P.2ClH.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h2*14H,1-6H3;2*1H;;/q;;;;+2;/p-2
InChIKey :ORDFDLUOXDTTTD-UHFFFAOYSA-L
SMILES :C(P1([Pd+2](P(C(C)(C)C)(C(C)(C)C)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]18C9=3)([Cl-])[Cl-])C(C)(C)C)(C)(C)C
CAS DataBase Reference :95408-45-0

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Coupling reactions, Suzuki couplings.Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene] palladium(II) is used as a catalyst in Suzuki-cross coupling reactions, which involve reaction of aromatic halides with methyliminodiacetic acid derivatives. it is also used as a catalyst for the preparation of chalcones. It is used in the preparation of (bisphosphinometallocene)-palladium(II) chloride complexes, which used as a starting material for the Buchwald-Hartwig reaction.

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