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ChemicalBook >> CAS DataBase List >> Diisobutylaluminium hydride

Diisobutylaluminium hydride

Diisobutylaluminium hydride price.
  • $22.4 - $2740
  • Product name: Diisobutylaluminium hydride
  • CAS: 1191-15-7
  • MF: C8H19Al
  • MW: 142.22
  • EINECS:214-729-9
  • MDL Number:MFCD00008928
  • Synonyms:Diisobutylaluminium hydride, 1.1M solution in cyclohexane, AcroSeal;Diisobutylaluminium hydride, 1M solution in hexane, AcroSeal;Diisobutylaluminium hydride, 1.0M solution in heptane, AcroSeal;DIISOBUTYLALUMINUM HYDRIDE: 20% (CA. 1M) SOLUTION IN TOLUENE;DIISOBUYTL AMUMINIUM HYDRIDE;Diisobutylaluminum hydride,reagent grade;DiisobutylaluMiniuM hydride, 1.1M solution in cyclohexane, AcroSeal 800ML;DiisobutylaluMiniuM hydride, 1M solution in hexane, AcroSeal 400ML
52 prices
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  • Alfa Aesar
  • Sigma-Aldrich
  • Strem Chemicals
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  • 50ml
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  • ManufacturerAlfa Aesar
  • Product number042593
  • Product descriptionDiisobutylaluminum hydride, 1M solution in hexane, packaged under Argon in resealable ChemSeal? bottles
  • Packaging50ml
  • Price$22.4
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042592
  • Product descriptionDiisobutylaluminum hydride, 25% w/w in hexane, packaged under Argon in resealable ChemSeal? bottles
  • Packaging50ml
  • Price$22.4
  • Updated2021-12-16
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  • ManufacturerAlfa Aesar
  • Product number042589
  • Product descriptionDiisobutylaluminum hydride, 1M solution in hexane
  • Packaging50ml
  • Price$24.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042588
  • Product descriptionDiisobutylaluminum hydride, 25% w/w in hexane
  • Packaging50ml
  • Price$25.5
  • Updated2023-06-20
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  • ManufacturerAlfa Aesar
  • Product number042591
  • Product descriptionDiisobutylaluminum hydride, 1M solution in toluene, packaged under Argon in resealable ChemSeal? bottles
  • Packaging50ml
  • Price$45.7
  • Updated2023-06-20
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  • ManufacturerAlfa Aesar
  • Product numberH36141
  • Product descriptionDiisobutylaluminum hydride, 1.2M solution in toluene packagedunderNitrogeninresealableAcroSeal[tbottles
  • Packaging100ml
  • Price$63.9
  • Updated2021-12-16
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  • ManufacturerAlfa Aesar
  • Product numberH37222
  • Product descriptionDiisobutylaluminum hydride, 1M solution in hexane packaged under Nitrogen in resealable AcroSeal[t bottles
  • Packaging800ml
  • Price$380
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH37222
  • Product descriptionDiisobutylaluminum hydride, 1M solution in hexane packaged under Nitrogen in resealable AcroSeal[t bottles
  • Packaging400ml
  • Price$217
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042593
  • Product descriptionDiisobutylaluminum hydride, 1M solution in hexane, packaged under Argon in resealable ChemSeal? bottles
  • Packaging800ml
  • Price$257
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042592
  • Product descriptionDiisobutylaluminum hydride, 25% w/w in hexane, packaged under Argon in resealable ChemSeal? bottles
  • Packaging800ml
  • Price$257
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH36141
  • Product descriptionDiisobutylaluminum hydride, 1.2M solution in toluene packagedunderNitrogeninresealableAcroSeal[tbottles
  • Packaging800ml
  • Price$282
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH37108
  • Product descriptionDiisobutylaluminumhydride,1.1Mincyclohexane packagedunderNitrogeninresealableAcroSeal[tbottles
  • Packaging800ml
  • Price$306
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product number042588
  • Product descriptionDiisobutylaluminum hydride, 25% w/w in hexane
  • Packaging1L
  • Price$316
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042592
  • Product descriptionDiisobutylaluminum hydride, 25% w/w in hexane, packaged under Argon in resealable ChemSeal? bottles
  • Packaging200ml
  • Price$112
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042593
  • Product descriptionDiisobutylaluminum hydride, 1M solution in hexane, packaged under Argon in resealable ChemSeal? bottles
  • Packaging200ml
  • Price$112
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042591
  • Product descriptionDiisobutylaluminum hydride, 1M solution in toluene, packaged under Argon in resealable ChemSeal? bottles
  • Packaging200ml
  • Price$123
  • Updated2023-06-20
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 042593 Diisobutylaluminum hydride, 1M solution in hexane, packaged under Argon in resealable ChemSeal? bottles 50ml $22.4 2021-12-16 Buy
Alfa Aesar 042592 Diisobutylaluminum hydride, 25% w/w in hexane, packaged under Argon in resealable ChemSeal? bottles 50ml $22.4 2021-12-16 Buy
Alfa Aesar 042589 Diisobutylaluminum hydride, 1M solution in hexane 50ml $24.5 2021-12-16 Buy
Alfa Aesar 042588 Diisobutylaluminum hydride, 25% w/w in hexane 50ml $25.5 2023-06-20 Buy
Alfa Aesar 042591 Diisobutylaluminum hydride, 1M solution in toluene, packaged under Argon in resealable ChemSeal? bottles 50ml $45.7 2023-06-20 Buy
Alfa Aesar H36141 Diisobutylaluminum hydride, 1.2M solution in toluene packagedunderNitrogeninresealableAcroSeal[tbottles 100ml $63.9 2021-12-16 Buy
Alfa Aesar H37222 Diisobutylaluminum hydride, 1M solution in hexane packaged under Nitrogen in resealable AcroSeal[t bottles 800ml $380 2023-06-20 Buy
Alfa Aesar H37222 Diisobutylaluminum hydride, 1M solution in hexane packaged under Nitrogen in resealable AcroSeal[t bottles 400ml $217 2023-06-20 Buy
Alfa Aesar 042593 Diisobutylaluminum hydride, 1M solution in hexane, packaged under Argon in resealable ChemSeal? bottles 800ml $257 2021-12-16 Buy
Alfa Aesar 042592 Diisobutylaluminum hydride, 25% w/w in hexane, packaged under Argon in resealable ChemSeal? bottles 800ml $257 2021-12-16 Buy
Alfa Aesar H36141 Diisobutylaluminum hydride, 1.2M solution in toluene packagedunderNitrogeninresealableAcroSeal[tbottles 800ml $282 2021-12-16 Buy
Alfa Aesar H37108 Diisobutylaluminumhydride,1.1Mincyclohexane packagedunderNitrogeninresealableAcroSeal[tbottles 800ml $306 2024-03-01 Buy
Alfa Aesar 042588 Diisobutylaluminum hydride, 25% w/w in hexane 1L $316 2023-06-20 Buy
Alfa Aesar 042592 Diisobutylaluminum hydride, 25% w/w in hexane, packaged under Argon in resealable ChemSeal? bottles 200ml $112 2021-12-16 Buy
Alfa Aesar 042593 Diisobutylaluminum hydride, 1M solution in hexane, packaged under Argon in resealable ChemSeal? bottles 200ml $112 2021-12-16 Buy
Alfa Aesar 042591 Diisobutylaluminum hydride, 1M solution in toluene, packaged under Argon in resealable ChemSeal? bottles 200ml $123 2023-06-20 Buy

Properties

Melting point :-70 °C
Boiling point :65 °C
Density :1.23 g/mL at 25 °C
vapor pressure :13.3Pa at 90℃
Flash point :40 °F
storage temp. :2-8°C
solubility :Miscible with organic solvents.
form :Solution
color :Clear
Specific Gravity :0.860
Water Solubility :vigorous reaction
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Sensitive :Air Sensitive/Heat Sensitive
BRN :4123663
Exposure limits :ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) InChIKey :AZWXAPCAJCYGIA-UHFFFAOYSA-N
LogP :4.22
CAS DataBase Reference :1191-15-7(CAS DataBase Reference)
NIST Chemistry Reference :Diisobutylaluminum hydride(1191-15-7)
EPA Substance Registry System :Diisobutylaluminum hydride (1191-15-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P370+P378 In case of fire: Use … for extinction.

Description

Reducing agentDiisobutylaluminum hydride, 1M solution in hexane is used in Pd-catalyzed reductive debromination of secondary alkyl bromides, O-debenzylation and ring opening of perbenzylated furanosides. It is involved in the in situ generation of HZrCpCl by reacting with ZrCpCl. It is useful in organic synthesis for a variety of reductions, including converting esters and nitriles to aldehydes. Also, used in the reduction of alpha-beta unsaturated esters to their corresponding allylic alcohols.

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