2-甲基喹啉(91-63-4)質(zhì)譜(MS)
InChI:InChI=1S/C10H9N/c1-8-6-7-9-4-2-3-5-10(9)11-8/h2-7H,1H3
InChIKey: SMUQFGGVLNAIOZ-UHFFFAOYSA-N
Smiles:N1C2C(=CC=CC=2)C=CC=1C
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Mass
MS-NW-0146
2-methylquinoline
C10H9N (Mass of molecular ion: 143)
Source Temperature: 200 °C
Sample Temperature: 75 °C
Reservoir, 75 eV
27.0 1.3
28.0 1.1
38.0 1.3
39.0 4.4
50.0 5.1
51.0 6.5
52.0 1.8
57.5 1.1
58.5 3.6
62.0 2.0
63.0 4.8
64.0 1.3
65.0 1.3
70.5 1.9
71.5 3.9
74.0 2.8
75.0 5.5
76.0 4.9
77.0 4.4
87.0 1.0
88.0 1.0
89.0 3.7
90.0 2.1
101.0 5.9
102.0 3.3
103.0 1.1
113.0 1.0
114.0 1.3
115.0 14.4
116.0 6.6
117.0 3.5
128.0 14.6
129.0 2.4
140.0 2.2
141.0 1.4
142.0 11.2
143.0 100.0
144.0 11.3
400 MHz in CDCl3
90 MHz in CDCl3
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| 1H NMR |
399.65 MHz |
| C10 H9 N
|
24.5 mg : 0.5 ml CDCl3
|
| 2-methylquinoline
|
 |
Assign. Shift(ppm)
A 8.03
B 7.759
C 7.677
D 7.475
E 7.271
F 2.745
|
Hz ppm Int.
3213.26 8.041 203
3212.77 8.039 202
3204.96 8.020 224
3204.47 8.019 218
3106.20 7.773 71
3104.49 7.769 82
3097.78 7.752 86
3096.31 7.748 88
3076.66 7.699 48
3075.32 7.696 44
3069.82 7.682 57
3068.36 7.678 103
3067.02 7.675 44
3061.40 7.661 48
3060.06 7.657 51
2994.75 7.494 58
2993.77 7.491 55
2987.79 7.477 55
2986.69 7.474 94
2985.47 7.471 55
2979.74 7.456 42
2978.52 7.453 41
2909.79 7.281 151
2901.37 7.260 138
1097.29 2.746 1000
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| 1H NMR |
89.56 MHz |
| C10 H9 N
|
0.024 g : 0.5 ml CDCl3
|
| 2-methylquinoline
|
|
Assign. Shift(ppm)
A 8.02
B 7.75
C 7.67
D 7.47
E 7.265
F 2.739
|
Hz ppm Int.
722.50 8.068 147
714.19 7.975 195
699.50 7.811 41
697.81 7.792 46
695.19 7.763 41
693.13 7.740 47
690.13 7.706 97
687.88 7.681 98
686.88 7.670 40
686.25 7.663 37
680.00 7.593 67
678.38 7.575 37
675.06 7.538 75
673.69 7.523 72
667.88 7.458 61
666.75 7.445 53
666.00 7.437 38
654.25 7.306 161
645.88 7.212 116
245.38 2.740 1000