2924-16-5

3-氟苯肼鹽酸(2924-16-5)紅外圖譜(IR2)

產(chǎn)品名稱:3-氟苯肼鹽酸

CAS:2924-16-5

分子式:C6H8ClFN2

分子量: 162.59

InChI:InChI=1S/C6H7FN2.ClH/c7-5-2-1-3-6(4-5)9-8;/h1-4,9H,8H2;1H

InChIKey: SKVGLOFWEJFQKU-UHFFFAOYSA-N

Smiles:C1(NN)=CC=CC(F)=C1.Cl

Mass

MS-NW-6879          
m-fluorophenylhydrazine hydrochloride
C6H7FN2 HCl         (Mass of molecular ion:    126)

   Source Temperature: 180 °C
   Sample Temperature: 120 °C
   Direct, 75 eV

      17.0       1.1
      18.0       4.2
      27.0       1.2
      28.0       2.3
      29.0       8.1
      30.0       2.4
      31.0       5.4
      35.0       5.9
      36.0      26.4
      37.0       2.8
      38.0       8.7
      39.0       4.8
      49.0       1.1
      50.0       6.9
      51.0       6.6
      52.0       3.2
      56.0       1.9
      57.0      11.8
      61.0       2.5
      62.0       4.0
      63.0       8.2
      64.0       2.5
      65.0       1.2
      68.0       2.4
      69.0       3.9
      70.0       5.4
      71.0       1.6
      74.0       3.5
      75.0      12.2
      76.0       1.9
      77.0       9.1
      78.0       1.8
      79.0       1.0
      81.0       4.2
      82.0       8.4
      83.0      41.8
      84.0       4.7
      89.0       3.2
      90.0       2.2
      94.0       1.5
      95.0      14.3
      96.0      18.9
      97.0       9.1
      98.0       4.4
      99.0       1.9
     108.0       1.8
     109.0      18.5
     110.0      28.0
     111.0      10.4
     124.0       1.2
     125.0       5.6
     126.0     100.0
     127.0       7.3

400 MHz in DMSO-d6

90 MHz in DMSO-d6

¹H NMR	399.65 MHz
C₆ H₇ F N₂	0.021 g : 0.5 ml DMSO-d₆
m-fluorophenylhydrazine hydrochloride

    Assign.     Shift(ppm)

      A            10.50
      B             8.7
      C             7.297
      D             6.874
      E             6.831
      G             6.730

     Hz     ppm     Int.

   4197.26  10.503   1000
   2933.41   7.340     33
   2933.05   7.340     40
   2932.50   7.338     34
   2931.95   7.337     32
   2931.58   7.336     34
   2931.03   7.334     38
   2930.48   7.333     44
   2930.11   7.332     50
   2928.10   7.327    311
   2924.80   7.319     83
   2924.25   7.318     78
   2921.14   7.310    388
   2920.04   7.307    715
   2913.26   7.290    657
   2911.80   7.286    546
   2907.77   7.276     75
   2907.40   7.275     72
   2905.02   7.269    342
   2902.27   7.263     50
   2764.17   6.917     30
   2761.42   6.910     33
   2761.05   6.909     33
   2760.69   6.908     37
   2760.32   6.907     37
   2759.95   6.906     38
   2759.40   6.905     47
   2759.04   6.904     49
   2758.67   6.903     56
   2755.92   6.896    345
   2753.73   6.891    665
   2751.53   6.885    480
   2747.50   6.875    104
   2744.57   6.868    347
   2743.83   6.866    306
   2742.37   6.862    670
   2740.17   6.857    521
   2737.24   6.850    161
   2734.86   6.844    752
   2733.39   6.840    615
   2732.66   6.838    612
   2726.62   6.823    643
   2725.33   6.820    581
   2724.60   6.818    577
   2719.11   6.804     33
   2705.37   6.770     30
   2705.00   6.769     30
   2703.90   6.766     40
   2703.35   6.765     44
   2699.32   6.755    334
   2696.94   6.749    329
   2694.75   6.743    123
   2693.83   6.741    107
   2690.53   6.733    566
   2688.70   6.728    579
   2685.22   6.719    104
   2682.29   6.712    322
   2680.46   6.708    290
   2679.73   6.706    293
   2677.34   6.700     56

¹H NMR	89.56 MHz
C₆ H₇ F N₂	0.034 g : 0.5 ml DMSO-d₆
m-fluorophenylhydrazine hydrochloride

    Assign.     Shift(ppm)

      A            10.5
      B             7.283
      C          6.98 to 6.78
      D             6.72

     Hz     ppm     Int.

    942.19  10.521    451
    665.58   7.432    185
    658.83   7.357    253
    657.36   7.340    453
    650.32   7.262    444
    649.74   7.255    417
    642.26   7.172    311
    625.24   6.982    251
    623.19   6.959    480
    620.99   6.934    439
    617.18   6.892    604
    616.30   6.882    606
    614.10   6.857    482
    611.75   6.831    864
    609.70   6.808   1000
    605.59   6.762    219
    603.24   6.736    501
    601.04   6.712    390
    595.03   6.644    230
    593.42   6.626    200
    592.98   6.622    201

KBr disc