10420-89-0

(S)-(-)-1-(1-萘基)乙胺(10420-89-0)質(zhì)譜(MS)

產(chǎn)品名稱:(S)-(-)-1-(1-萘基)乙胺

CAS:10420-89-0

分子式:C12H13N

分子量: 171.24

InChI:InChI=1/C12H13N/c1-9(13)11-8-4-6-10-5-2-3-7-12(10)11/h2-9H,13H2,1H3/t9-/s3

InChIKey: RTCUCQWIICFPOD-DJEYLCQNNA-N

Smiles:[C@H](C1=CC=CC2=CC=CC=C12)(N)C |&1:0,r|

Mass

MS-NW-9259          
S-(-)-1-(1-naphthyl)ethylamine
C12H13N             (Mass of molecular ion:    171)

   Source Temperature: 250 °C
   Sample Temperature: 160 °C
   Reservoir, 75 eV

      28.0       2.6
      42.0       5.1
      43.0       4.1
      44.0      10.0
      51.0       2.2
      63.0       2.7
      64.0       1.7
      65.0       2.5
      71.5       1.7
      74.0       1.0
      75.0       1.9
      76.0       2.7
      76.5       2.3
      77.0       6.9
      77.5       5.3
      78.0      11.3
      78.5       1.2
      83.5       1.8
      84.5       3.2
     101.0       1.7
     102.0       1.5
     115.0       2.2
     126.0       3.4
     127.0      12.5
     128.0      19.0
     129.0      39.0
     130.0       4.8
     139.0       1.1
     141.0       1.3
     151.0       1.9
     152.0       5.6
     153.0       7.9
     154.0       8.8
     155.0       4.4
     156.0     100.0
     157.0      12.1
     167.0       1.1
     168.0       1.8
     170.0       5.6
     171.0      17.1
     172.0       2.3

400 MHz in CDCl3

¹H NMR	399.65 MHz
C₁₂ H₁₃ N	0.05 ml : 0.5 ml CDCl₃
S-(-)-1-(1-naphthyl)ethylamine

    Assign.     Shift(ppm)

      A             8.093
      B             7.833
      C             7.707
      D             7.611
      E     *1      7.487
      F     *1      7.45
      G             7.44
      J             4.895
      K             1.57
      L             1.502
     
     ASSIGNED BY H-H COSY.

     Hz     ppm     Int.

   3239.01   8.105    132
   3230.59   8.084    142
   3135.13   7.845    119
   3134.40   7.843    114
   3133.67   7.842    111
   3127.32   7.826    146
   3125.61   7.821    142
   3084.47   7.718    142
   3076.29   7.698    167
   3045.78   7.622    144
   3038.57   7.604    174
   3001.59   7.511     68
   3000.12   7.507     82
   2994.87   7.494    140
   2993.29   7.490    167
   2991.70   7.486     79
   2986.57   7.473    154
   2984.86   7.469    142
   2982.67   7.464    152
   2980.96   7.459    265
   2975.83   7.447     93
   2974.49   7.443    181
   2973.27   7.440    305
   2967.90   7.427     80
   2966.55   7.423     81
   2965.21   7.420    136
   1966.43   4.921     49
   1959.84   4.904    144
   1953.25   4.888    146
   1946.66   4.871     52
    625.85   1.566    100
    625.24   1.565    100
    624.39   1.563     98
    617.55   1.546     55
    612.18   1.532     35
    610.96   1.529     39
    603.88   1.512    980
    597.29   1.495   1000

KBr disc