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ChemicalBook >> CAS DataBase List >> Tri-tert-butylphosphine

Tri-tert-butylphosphine

Tri-tert-butylphosphine price.
  • $45 - $1025.99
  • Product name: Tri-tert-butylphosphine
  • CAS: 13716-12-6
  • MF: C12H27P
  • MW: 202.32
  • EINECS:237-266-4
  • MDL Number:MFCD00015006
  • Synonyms:Phosphine, tris(1,1-dimethylethyl)-;TRI-TERT-BUTYL-PHOSPHANE;TRI-TERT-BUTYLPHOSPHINE;tris(1,1-dimethylethyl)phosphine ;TRI-TERT-BUTYLPHOSPHINE, 1M IN TOLUENE;TRI-TERT-BUTYLPHOSPHINE, TECH., 90%;TERT-BUTYLPHOSPHINE, ELEC. GR., 99.9995%;Tri-t-butylphosphine,99%
26 prices
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Brand
  • Acrotein
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
  • TRC
Package
  • 500mg
  • 1g
  • 2g
  • 5g
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  • 10ml
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  • 500mL
  • ManufacturerAcrotein
  • Product numberAC-3065
  • Product descriptionTri-tert-butylphosphine 97%
  • Packaging100mL
  • Price$330
  • Updated2021-12-16
  • Buy
  • ManufacturerAcrotein
  • Product numberAC-3065
  • Product descriptionTri-tert-butylphosphine 97%
  • Packaging500mL
  • Price$990
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number010178
  • Product descriptionTri-tert-butylphosphine 98%
  • Packaging1g
  • Price$121.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number010178
  • Product descriptionTri-tert-butylphosphine 98%
  • Packaging5g
  • Price$380
  • Updated2024-03-01
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOPC0001063
  • Product descriptionTRI-T-BUTYLPHOSPHINE 95.00%
  • Packaging1G
  • Price$179.66
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOPC0001063
  • Product descriptionTRI-T-BUTYLPHOSPHINE 95.00%
  • Packaging5G
  • Price$1025.99
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number104464
  • Product descriptionTri-tert-butylphosphine solution 1.0 M in toluene
  • Packaging5g
  • Price$50
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number570958
  • Product descriptionTri-tert-butylphosphine 98%
  • Packaging1g
  • Price$91.8
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number655325
  • Product descriptionTri-tert-butylphosphine solution 1.0 M in toluene
  • Packaging10ml
  • Price$140
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number570958
  • Product descriptionTri-tert-butylphosphine 98%
  • Packaging5g
  • Price$232
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number570958
  • Product descriptionTri-tert-butylphosphine 98%
  • Packaging10g
  • Price$242
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number901441
  • Product descriptionTri-tert-butylphosphine solution 1.0 M in 2-methyltetrahydrofuran
  • Packaging25ml
  • Price$263
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number901438
  • Product descriptionTri-tert-butylphosphine solution 1.0?M in THF
  • Packaging25mL
  • Price$264
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number655325
  • Product descriptionTri-tert-butylphosphine solution 1.0 M in 2-methyltetrahydrofuran
  • Packaging25ml
  • Price$335
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number655325
  • Product descriptionTri-tert-butylphosphine solution 1.0 M in toluene
  • Packaging50ml
  • Price$508
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-5813
  • Product descriptionTri-t-butylphosphine, min. 98%
  • Packaging1g
  • Price$64
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AC-3065 Tri-tert-butylphosphine 97% 100mL $330 2021-12-16 Buy
Acrotein AC-3065 Tri-tert-butylphosphine 97% 500mL $990 2021-12-16 Buy
Alfa Aesar 010178 Tri-tert-butylphosphine 98% 1g $121.65 2024-03-01 Buy
Alfa Aesar 010178 Tri-tert-butylphosphine 98% 5g $380 2024-03-01 Buy
American Custom Chemicals Corporation OPC0001063 TRI-T-BUTYLPHOSPHINE 95.00% 1G $179.66 2021-12-16 Buy
American Custom Chemicals Corporation OPC0001063 TRI-T-BUTYLPHOSPHINE 95.00% 5G $1025.99 2021-12-16 Buy
Oakwood 104464 Tri-tert-butylphosphine solution 1.0 M in toluene 5g $50 2021-12-16 Buy
Sigma-Aldrich 570958 Tri-tert-butylphosphine 98% 1g $91.8 2024-03-01 Buy
Sigma-Aldrich 655325 Tri-tert-butylphosphine solution 1.0 M in toluene 10ml $140 2024-03-01 Buy
Sigma-Aldrich 570958 Tri-tert-butylphosphine 98% 5g $232 2024-03-01 Buy
Sigma-Aldrich 570958 Tri-tert-butylphosphine 98% 10g $242 2024-03-01 Buy
Sigma-Aldrich 901441 Tri-tert-butylphosphine solution 1.0 M in 2-methyltetrahydrofuran 25ml $263 2024-03-01 Buy
Sigma-Aldrich 901438 Tri-tert-butylphosphine solution 1.0?M in THF 25mL $264 2024-03-01 Buy
Sigma-Aldrich 655325 Tri-tert-butylphosphine solution 1.0 M in 2-methyltetrahydrofuran 25ml $335 2024-03-01 Buy
Sigma-Aldrich 655325 Tri-tert-butylphosphine solution 1.0 M in toluene 50ml $508 2024-03-01 Buy
Strem Chemicals 15-5813 Tri-t-butylphosphine, min. 98% 1g $64 2024-03-01 Buy

Properties

Melting point :30-35 °C(lit.)
Boiling point :102-103 °C13 mm Hg(lit.)
Density :0.861 g/mL at 25 °C
Flash point :1 °F
storage temp. :Flammables area
form :solid
Specific Gravity :0.68
Water Solubility :insoluble
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
BRN :1738613
InChIKey :BWHDROKFUHTORW-UHFFFAOYSA-N
CAS DataBase Reference :13716-12-6(CAS DataBase Reference)
NIST Chemistry Reference :Tri-tert-butylphosphine(13716-12-6)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.

Description

Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

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