Tri-tert-butylphosphine
- CAS No.
- 13716-12-6
- Chemical Name:
- Tri-tert-butylphosphine
- Synonyms
- P(t-Bu)3;TTBP;TRI-T-BUTYLPHOSPHINE;Tri-tert-butyL;Tris(tert-butyl)phosphine;Butylphosphine;Uncle Ding Jilin;ri-tert-butylphosphine;TRI-TERT-BUTYLPHOSPHINE;Tri-t-butylphosphosphin
- CBNumber:
- CB9483150
- Molecular Formula:
- C12H27P
- Molecular Weight:
- 202.32
- MDL Number:
- MFCD00015006
- MOL File:
- 13716-12-6.mol
- MSDS File:
- SDS
Melting point | 30-35 °C(lit.) |
---|---|
Boiling point | 102-103 °C13 mm Hg(lit.) |
Density | 0.861 g/mL at 25 °C |
Flash point | 1 °F |
storage temp. | Flammables area |
form | solid |
Specific Gravity | 0.68 |
Water Solubility | insoluble |
Sensitive | Air & Moisture Sensitive |
Hydrolytic Sensitivity | 9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required |
BRN | 1738613 |
InChIKey | BWHDROKFUHTORW-UHFFFAOYSA-N |
CAS DataBase Reference | 13716-12-6(CAS DataBase Reference) |
NIST Chemistry Reference | Tri-tert-butylphosphine(13716-12-6) |
UNSPSC Code | 12352128 |
NACRES | NA.22 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H250-H314 | |||||||||
Precautionary statements | P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P370+P378 | |||||||||
Hazard Codes | F,C | |||||||||
Risk Statements | 17-34-67-65-63-48/20-11 | |||||||||
Safety Statements | 26-45-62-36/37/39-25-43-27-16 | |||||||||
RIDADR | UN 2846 4.2/PG 1 | |||||||||
WGK Germany | 3 | |||||||||
F | 10-19-23 | |||||||||
HazardClass | 4.2 | |||||||||
PackingGroup | I | |||||||||
HS Code | 29319090 | |||||||||
NFPA 704 |
|
Tri-tert-butylphosphine price More Price(26)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 901438 | Tri-tert-butylphosphine solution 1.0?M in THF | 13716-12-6 | 25mL | $264 | 2024-03-01 | Buy |
Sigma-Aldrich | 570958 | Tri-tert-butylphosphine 98% | 13716-12-6 | 1g | $91.8 | 2024-03-01 | Buy |
Sigma-Aldrich | 570958 | Tri-tert-butylphosphine 98% | 13716-12-6 | 5g | $232 | 2024-03-01 | Buy |
Alfa Aesar | 010178 | Tri-tert-butylphosphine 98% | 13716-12-6 | 1g | $121.65 | 2024-03-01 | Buy |
Alfa Aesar | 010178 | Tri-tert-butylphosphine 98% | 13716-12-6 | 5g | $380 | 2024-03-01 | Buy |
Tri-tert-butylphosphine Chemical Properties,Uses,Production
Reaction
Useful as a ligand in a variety of palladium-catalyzed C-N, C-O and C-C bond-forming reactions under mild conditions.
Chemical Properties
Colorless to light yellow liqui
Uses
Valuable ligand for several coupling reactions. This product is offered as the THF solution for more convenient handling.
Uses
Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.
reaction suitability
reagent type: ligand
reaction type: Addition Reactions
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Stille Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
Tri-tert-butylphosphine Preparation Products And Raw materials
Raw materials
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Preparation Products
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Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-18789408387 | 1057@dideu.com | China | 3889 | 58 |
Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 7709 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29792 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18951 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21632 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | FandaChem@Gmail.com | China | 8741 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32965 | 60 |
AB PharmaTech,LLC | 323-480-4688 | sales@acrospharmatech.com | United States | 989 | 55 |
Shanxi Naipu Import and Export Co.,Ltd | +86-13734021967 +8613734021967 | kaia@neputrading.com | China | 1001 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29871 | 58 |
View Lastest Price from Tri-tert-butylphosphine manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2025-02-08 | Tri-tert-butylphosphine
13716-12-6
|
US $589.00 / g | 1g | 0.99 | 1kg | Shanghai UCHEM Inc. | ||
2024-05-26 | Tri-tert-butylphosphine
13716-12-6
|
US $1.00 / KG | 1KG | 98% | 20T | Shaanxi Dideu Medichem Co. Ltd | ||
2023-08-16 | Tri-tert-butylphosphine
13716-12-6
|
US $1.00 / KG | 1KG | >99% | 2000T | Weijer International Trade (Hebei) Co., Ltd |
- Tri-tert-butylphosphine
13716-12-6
- US $589.00 / g
- 0.99
- Shanghai UCHEM Inc.
- Tri-tert-butylphosphine
13716-12-6
- US $1.00 / KG
- 98%
- Shaanxi Dideu Medichem Co. Ltd
- Tri-tert-butylphosphine
13716-12-6
- US $1.00 / KG
- >99%
- Weijer International Trade (Hebei) Co., Ltd
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