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ChemicalBook >> CAS DataBase List >> 1,1'-Bis(diisopropylphosphino)ferrocene

1,1'-Bis(diisopropylphosphino)ferrocene

1,1'-Bis(diisopropylphosphino)ferrocene price.
  • $21 - $711
  • Product name: 1,1'-Bis(diisopropylphosphino)ferrocene
  • CAS: 97239-80-0
  • MF: C22H36FeP210*
  • MW: 418.31
  • EINECS:677-500-6
  • MDL Number:MFCD02684559
  • Synonyms:BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON;1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98%;1,1'-Bis(diisopropylphosphino)ferrocene,98%;1,1'-Bis(di-i-propylphosphino)ferrocene,min.98%;1,1'-Bis[bis(1-methylethyl)phosphino]ferrocene;Ferrocene,1,1'-bis[bis(1-Methylethyl)phosphino]-
24 prices
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  • AK Scientific
  • Alfa Aesar
  • Arctom
  • Biosynth Carbosynth
  • ChemScene
  • ChemSupplyAustralia
  • Crysdot
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 2mg
  • 100mg
  • 250mg
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  • 1g
  • 2g
  • 5g
  • 10g
  • 25g
  • ManufacturerAK Scientific
  • Product numberZ2231
  • Product description1,1'-Bis(di-i-propylphosphino)ferrocene
  • Packaging1g
  • Price$161
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberZ2231
  • Product description1,1'-Bis(di-i-propylphosphino)ferrocene
  • Packaging5g
  • Price$614
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27057
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene, 98%
  • Packaging1g
  • Price$169
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27057
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene, 98%
  • Packaging5g
  • Price$571
  • Updated2023-06-20
  • Buy
  • ManufacturerArctom
  • Product numberSY009820
  • Product description1,1’-Bis(diisopropylphosphino)ferrocene ≥95%
  • Packaging10g
  • Price$213
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB60776
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene
  • Packaging250mg
  • Price$60
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB60776
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene
  • Packaging500mg
  • Price$104
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB60776
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene
  • Packaging1g
  • Price$181
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB60776
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene
  • Packaging2g
  • Price$308
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB60776
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene
  • Packaging5G
  • Price$616
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0031981
  • Product description1,1'-Bis(di-isopropylphosphino)ferrocene ≥98.0%
  • Packaging1g
  • Price$21
  • Updated2021-12-16
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  • ManufacturerChemScene
  • Product numberCS-0031981
  • Product description1,1'-Bis(di-isopropylphosphino)ferrocene ≥98.0%
  • Packaging5g
  • Price$72
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0031981
  • Product description1,1'-Bis(di-isopropylphosphino)ferrocene ≥98.0%
  • Packaging25g
  • Price$264
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300279
  • Product description1,1'-Bis(di-i-propylphosphino)ferrocene, 98%
  • Packaging500mg
  • Price$48.4
  • Updated2021-12-16
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  • ManufacturerCrysdot
  • Product numberCD52000006
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene 97%
  • Packaging1g
  • Price$120
  • Updated2021-12-16
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  • ManufacturerCrysdot
  • Product numberCD52000006
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene 97%
  • Packaging5g
  • Price$150
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific Z2231 1,1'-Bis(di-i-propylphosphino)ferrocene 1g $161 2021-12-16 Buy
AK Scientific Z2231 1,1'-Bis(di-i-propylphosphino)ferrocene 5g $614 2021-12-16 Buy
Alfa Aesar H27057 1,1'-Bis(diisopropylphosphino)ferrocene, 98% 1g $169 2023-06-20 Buy
Alfa Aesar H27057 1,1'-Bis(diisopropylphosphino)ferrocene, 98% 5g $571 2023-06-20 Buy
Arctom SY009820 1,1’-Bis(diisopropylphosphino)ferrocene ≥95% 10g $213 2021-12-16 Buy
Biosynth Carbosynth FB60776 1,1'-Bis(diisopropylphosphino)ferrocene 250mg $60 2021-12-16 Buy
Biosynth Carbosynth FB60776 1,1'-Bis(diisopropylphosphino)ferrocene 500mg $104 2021-12-16 Buy
Biosynth Carbosynth FB60776 1,1'-Bis(diisopropylphosphino)ferrocene 1g $181 2021-12-16 Buy
Biosynth Carbosynth FB60776 1,1'-Bis(diisopropylphosphino)ferrocene 2g $308 2021-12-16 Buy
Biosynth Carbosynth FB60776 1,1'-Bis(diisopropylphosphino)ferrocene 5G $616 2021-12-16 Buy
ChemScene CS-0031981 1,1'-Bis(di-isopropylphosphino)ferrocene ≥98.0% 1g $21 2021-12-16 Buy
ChemScene CS-0031981 1,1'-Bis(di-isopropylphosphino)ferrocene ≥98.0% 5g $72 2021-12-16 Buy
ChemScene CS-0031981 1,1'-Bis(di-isopropylphosphino)ferrocene ≥98.0% 25g $264 2021-12-16 Buy
ChemSupplyAustralia 300279 1,1'-Bis(di-i-propylphosphino)ferrocene, 98% 500mg $48.4 2021-12-16 Buy
Crysdot CD52000006 1,1'-Bis(diisopropylphosphino)ferrocene 97% 1g $120 2021-12-16 Buy
Crysdot CD52000006 1,1'-Bis(diisopropylphosphino)ferrocene 97% 5g $150 2021-12-16 Buy

Properties

Melting point :50-52 °C(lit.)
Flash point :>230 °F
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Powder
color :orange-yellow
Water Solubility :Insoluble in water.
InChI :InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
InChIKey :LPBBEMRSRONKMN-UHFFFAOYSA-N
SMILES :P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
CAS DataBase Reference :97239-80-0(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

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