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ChemicalBook >> CAS DataBase List >> (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide price.
  • $115 - $2165
  • Product name: (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
  • CAS: 864943-22-6
  • MF: C48H29O4P
  • MW: 700.72
  • EINECS:
  • MDL Number:MFCD12546016
  • Synonyms:(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide;(11bS)-4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxidedinaphtho[ 2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide,99%e.e.;(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate;SF110065;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d
6 prices
Selected condition：
Brand
  • Ambeed
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 50mg
  • 100mg
  • 250mg
  • 1g
  • 5g
  • ManufacturerAmbeed
  • Product numberA996076
  • Product description(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98%
  • Packaging5g
  • Price$2165
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA996076
  • Product description(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98%
  • Packaging1g
  • Price$625
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA996076
  • Product description(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98%
  • Packaging250mg
  • Price$215
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA996076
  • Product description(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98%
  • Packaging100mg
  • Price$115
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number700665
  • Product description(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
  • Packaging100mg
  • Price$158.4
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0552
  • Product description(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98% 98%
  • Packaging50mg
  • Price$271
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Ambeed A996076 (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98% 5g $2165 2021-12-16 Buy
Ambeed A996076 (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98% 1g $625 2021-12-16 Buy
Ambeed A996076 (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98% 250mg $215 2021-12-16 Buy
Ambeed A996076 (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98% 100mg $115 2021-12-16 Buy
Sigma-Aldrich 700665 (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide 100mg $158.4 2024-03-01 Buy
Strem Chemicals 15-0552 (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98% 98% 50mg $271 2024-03-01 Buy

Properties

Melting point :390-400°C
Density :1.46±0.1 g/cm3(Predicted)
storage temp. :-20°C
pka :1.11±0.20(Predicted)
optical activity :[α]22/D 44.0°, c = 1 in DMSO
CAS DataBase Reference :864943-22-6

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.

Description

Catalyst for:
  • Asymmetric hydrogenation cascade
  • Enantioselective Friedel-Crafts reaction
  • Asymmetric hydrogenation of 2-substituted quinolines
  • Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
  • Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
  • Asymmetric transfer hydrogenation of substituted quinoxalines