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ChemicalBook--->CAS DataBase List--->864943-22-6

864943-22-6

864943-22-6 Structure

864943-22-6 Structure
IdentificationBack Directory
[Name]

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
[CAS]

864943-22-6
[Synonyms]

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide,99%e.e.
(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate
(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxidedinaphtho[ 2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(11bS)-4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
[Molecular Formula]

C48H29O4P
[MDL Number]

MFCD12546016
[MOL File]

864943-22-6.mol
[Molecular Weight]

700.72
Chemical PropertiesBack Directory
[Melting point ]

390-400°C
[density ]

1.46±0.1 g/cm3(Predicted)
[storage temp. ]

?20°C
[pka]

1.11±0.20(Predicted)
[optical activity]

[α]22/D 44.0°, c = 1 in DMSO
[CAS DataBase Reference]

864943-22-6
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315
[Precautionary statements ]

P264-P280-P302+P352-P332+P313-P362+P364
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Catalyst for:
  • Asymmetric hydrogenation cascade
  • Enantioselective Friedel-Crafts reaction
  • Asymmetric hydrogenation of 2-substituted quinolines
  • Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
  • Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
  • Asymmetric transfer hydrogenation of substituted quinoxalines
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