| Identification | Back Directory | [Name]
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide | [CAS]
864943-22-6 | [Synonyms]
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide,99%e.e.
(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate
(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxidedinaphtho[
2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(11bS)-4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide | [Molecular Formula]
C48H29O4P | [MDL Number]
MFCD12546016 | [MOL File]
864943-22-6.mol | [Molecular Weight]
700.72 |
| Chemical Properties | Back Directory | [Melting point ]
390-400°C | [density ]
1.46±0.1 g/cm3(Predicted) | [storage temp. ]
?20°C | [form ]
solid | [pka]
1.11±0.20(Predicted) | [optical activity]
[α]22/D 44.0°, c = 1 in DMSO | [CAS DataBase Reference]
864943-22-6 |
| Hazard Information | Back Directory | [Uses]
Catalyst for:
- Asymmetric hydrogenation cascade
- Enantioselective Friedel-Crafts reaction
- Asymmetric hydrogenation of 2-substituted quinolines
- Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
- Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
- Asymmetric transfer hydrogenation of substituted quinoxalines
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