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ChemicalBook >> CAS DataBase List >> BIS(1,5-CYCLOOCTADIENE)NICKEL(0)

BIS(1,5-CYCLOOCTADIENE)NICKEL(0)

BIS(1,5-CYCLOOCTADIENE)NICKEL(0) price.
  • $31.6 - $974
  • Product name: BIS(1,5-CYCLOOCTADIENE)NICKEL(0)
  • CAS: 1295-35-8
  • MF: C16H24Ni
  • MW: 275.06
  • EINECS:215-072-0
  • MDL Number:MFCD00058902
  • Synonyms:Bis(1,5-cyclooctadiene)nickel(O), 98+%;Bis(1,5-cyclooctadiene)nickel(0) 1GR;Bis(1,5-cyclooctadiene)nickel(0) 5GR;Bis(1,5-cyclooctadiene)nickel (0),98% Ni(COD)2;bis(1,5-cyclooctadiene)-nicke ;Bis-1,5-cyclooctadienylnickel;Di(1,5-cyclooctadiene)nickel;Dicyclooctadiene nickel
22 prices
Selected condition:
Brand
  • Acrotein
  • Activate Scientific
  • Alfa Aesar
  • Alichem
  • Chemenu
  • Chem-Impex
  • ChemScene
  • ChemSupplyAustralia
  • Matrix Scientific
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 0.5g
  • 1g
  • 2g
  • 5g
  • 10g
  • 25g
  • 5each
  • ManufacturerAcrotein
  • Product numberAS00804
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0) 97%
  • Packaging10g
  • Price$458.34
  • Updated2021-12-16
  • Buy
  • ManufacturerAcrotein
  • Product numberAS00804
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0) 97%
  • Packaging5g
  • Price$275
  • Updated2021-12-16
  • Buy
  • ManufacturerActivate Scientific
  • Product numberAS107783
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0) 97%
  • Packaging1g
  • Price$101
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number039234
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0)
  • Packaging0.5g
  • Price$31.6
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number044157
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0), 96%
  • Packaging2g
  • Price$108
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number039234
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0)
  • Packaging2g
  • Price$108
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number044157
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0), 96%
  • Packaging10g
  • Price$466
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number039234
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0)
  • Packaging10g
  • Price$486
  • Updated2024-03-01
  • Buy
  • ManufacturerAlichem
  • Product number1295358
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0)
  • Packaging25g
  • Price$974
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM328799
  • Product description(1Z,5Z)-cycloocta-1,5-diene;nickel 95%+
  • Packaging25g
  • Price$672
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number40709
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0)(Waxencapsulated)(ca.0.05mmol/capsule)Hazmat
  • Packaging5G
  • Price$474.07
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0035192
  • Product descriptionNi(COD)2 ≥97.0%
  • Packaging1g
  • Price$68
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0035192
  • Product descriptionNi(COD)2 ≥97.0%
  • Packaging5g
  • Price$240
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0035192
  • Product descriptionNi(COD)2 ≥97.0%
  • Packaging10g
  • Price$385
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300025
  • Product descriptionBis(1,5-cyclooctadiene)nickel (0), 98%
  • Packaging1g
  • Price$31.9
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number167969
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0)
  • Packaging5g
  • Price$285
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AS00804 Bis(1,5-cyclooctadiene)nickel(0) 97% 10g $458.34 2021-12-16 Buy
Acrotein AS00804 Bis(1,5-cyclooctadiene)nickel(0) 97% 5g $275 2021-12-16 Buy
Activate Scientific AS107783 Bis(1,5-cyclooctadiene)nickel(0) 97% 1g $101 2021-12-16 Buy
Alfa Aesar 039234 Bis(1,5-cyclooctadiene)nickel(0) 0.5g $31.6 2021-12-16 Buy
Alfa Aesar 044157 Bis(1,5-cyclooctadiene)nickel(0), 96% 2g $108 2024-03-01 Buy
Alfa Aesar 039234 Bis(1,5-cyclooctadiene)nickel(0) 2g $108 2024-03-01 Buy
Alfa Aesar 044157 Bis(1,5-cyclooctadiene)nickel(0), 96% 10g $466 2024-03-01 Buy
Alfa Aesar 039234 Bis(1,5-cyclooctadiene)nickel(0) 10g $486 2024-03-01 Buy
Alichem 1295358 Bis(1,5-cyclooctadiene)nickel(0) 25g $974 2021-12-16 Buy
Chemenu CM328799 (1Z,5Z)-cycloocta-1,5-diene;nickel 95%+ 25g $672 2021-12-16 Buy
Chem-Impex 40709 Bis(1,5-cyclooctadiene)nickel(0)(Waxencapsulated)(ca.0.05mmol/capsule)Hazmat 5G $474.07 2021-12-16 Buy
ChemScene CS-0035192 Ni(COD)2 ≥97.0% 1g $68 2021-12-16 Buy
ChemScene CS-0035192 Ni(COD)2 ≥97.0% 5g $240 2021-12-16 Buy
ChemScene CS-0035192 Ni(COD)2 ≥97.0% 10g $385 2021-12-16 Buy
ChemSupplyAustralia 300025 Bis(1,5-cyclooctadiene)nickel (0), 98% 1g $31.9 2021-12-16 Buy
Matrix Scientific 167969 Bis(1,5-cyclooctadiene)nickel(0) 5g $285 2021-12-16 Buy

Properties

Melting point :60 °C (dec.)(lit.)
storage temp. :-20°C
solubility :Benzene (Partially Dissolved), THF (Slightly)
form :Shiny Crystalline Powder
color :Gold
Water Solubility :Soluble in benzene, toluene, terahydrofuran, ether, dimethyl formamide, hexamethylphosphoramide, N-methylpyrrolidinone. Insoluble in water.
Sensitive :Air Sensitive
Exposure limits :NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability :Air Sensitive
CAS DataBase Reference :1295-35-8(CAS DataBase Reference)
NIST Chemistry Reference :Nickel, bis[(1,2,5,6-«eta»)-1,5-cyclooctadiene]-(1295-35-8)
EPA Substance Registry System :Bis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]nickel (1295-35-8)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

Catalyst for isomerization and hydrosilyltion of unsaturated compounds. Co-catalyst for oligomerization/cyclooligomerization or polymerization of alkenes, Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. It is involved as a catalyst for asymmetric alpha-arylation and heteroarylation of ketones with chloroarenes, stereoselective borylative ketone-diene coupling, cycloaddition of benzamides with internal alkynes and methyl carboxylation of homopropargylic alcohols.

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