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??-D-???? ???????

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604-68-2
???:
??-D-???? ???????
???(??):
??-D-???????????;??-D-???????????
???:
Glucose pentaacetate
???(??):
alpha-D-Glucose pentaacetate;α-Pentacetylglucose;A-D-GLUCOSE PENTAACETATE;ALPHA-D-GLUCOPYRANOSE-PENTAACETATE;NSC 9290;FEMA 2524;NSC 119335;a-pentacetylglucose;GLUCOSE PENTAACETATE;Gastrodin Impurity 2
CBNumber:
CB9734003
???:
C16H22O11
??? ??:
390.34
MOL ??:
604-68-2.mol
MSDS ??:
SDS

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???
111-113 °C
??
97 º (c=1, CHCl3)
?? ?
435.58°C (rough estimate)
??
1.3984 (rough estimate)
???
0-0Pa at 20-50℃
FEMA
2524 | GLUCOSE PENTAACETATE
???
105.5 ° (C=1.5, MeOH)
?? ??
Sealed in dry,Room Temperature
???
?????: 0.1 g/mL, ??, ??
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??
??
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100.00%??. ?? ??
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optical activity
[α]20/D ≥+98°, c = 1 in ethanol
???
< 5G/L(25&C)
BRN
98852
LogP
1.87 at 25℃ and pH5.7
CAS ??????
604-68-2(CAS DataBase Reference)
NIST
«alpha»-D-Glucopyranose, pentaacetate(604-68-2)
EPA
.alpha.-D-Glucopyranose, pentaacetate (604-68-2)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn,Xi
?? ???? ?? 21-36/38-46-62-63
????? 24/25-53-36/37-26-25
WGK ?? 3
TSCA Yes
HS ?? 29400000
???? ?? KE-17752
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
2 0

??-D-???? ??????? MSDS


1,2,3,4,6-Penta-O-acetyl-alpha-D-glucopyranose

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white to light yellow crystal powde

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D-Glucose pentaacetate was reported to stimulate insulin release in rat pancreatic islets. Only α-D-glucose pentaacetate caused an immediate increase in insulin output. The β-anomer of D-glucose pentaacetate first transiently inhibited insulin release, this initial effect being followed by a secondary rise in secretory rate.

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Glucose-penta-acetate is a bitter principle in food products, mainly spice blends, condiments, alcoholic beverages, etc. The concentration is equivalent to about 100 to 1500 ppm in the finished consumer product.

Purification Methods

Crystallise it from MeOH, EtOH or three recrystallisations from 95% EtOH. [Wolfrom & Thompson Methods in Carbohydrate Chemistry II 212 1963, Academic Press, Beilstein 17/7 V 318.]

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