??(DI-TERT-BUTYL(4-????????)????)???????(II)
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??(DI-TERT-BUTYL(4-????????)????)???????(II) ??
- ?? ??
- Keep in dark place,Sealed in dry,Room Temperature
- ??? ??
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- InChI
- InChI=1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;
- InChIKey
- AWOFSUFKCXRJMV-UHFFFAOYSA-N
- SMILES
- P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)(C(C)(C)C)[Pd+2]([Cl-])([Cl-])P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)C(C)(C)C
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- ?? ? ???? ?? (GHS)
??(DI-TERT-BUTYL(4-????????)????)???????(II) C??? ??, ??, ??
??? ??
Yellow powder??
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium is useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.Synthesis
To a 500 mL reaction was added 10 g (1,5-cyclooctadiene) palladium dichloride, the reaction flask was replaced with a nitrogen atmosphere,19.6 g of di-tert-butyl-4-dimethylaminophenylphosphine and 200 mL of anhydrous tetrahydrofuran were added. The mixture was stirred at room temperature for 16 hours; There was a solid precipitation; filtration and drying gave a pale yellow powder product bis (di-tert-butyl-4-dimethylaminophenylphosphine) palladium chloride. The yield was 97 percent.??(DI-TERT-BUTYL(4-????????)????)???????(II) ?? ?? ? ???
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??(DI-TERT-BUTYL(4-????????)????)???????(II) ?? ??
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??(DI-TERT-BUTYL(4-????????)????)???????(II) ?? ??:
???? [?? (2- (? ?? ?? ??) ??) ???] ??? (II) ?? ?? ?? ? (2- ?? ?? ?? ?? ?? -3,6- ?? ?? -2 ', 4', 6'- ?? -i- ??? -1,1'- ? ??) (2'- ?? ??? -1,1'- ? ?? -2- ? ) ??? (II) (2'- ??? -1,1'- ? ?? -2- ?) ??? (II)? ??? (2- ?? ?? ?? ?? ?? -2 ', 4', 6'- ?? -i- ??? -1,1'- ? ??) ??? (2- ?? ?? ?? ?? ?? -2 ', 6'- ?? ?? -1,1'- ? ??) (2'- ??? -1,1'- ? ?? -2- ?) ??? (II) ???? [9,9- ??? -4,5- ?? (? ?? ?? ??) ? ??] ??? (II) ?-tert-butylphenylphosphine
DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
(S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97%
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)
DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II)
DICHLOROBIS(INDENYL)TITANIUM(IV)
Ruthenium(II) chloride mesitylene dimer
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
dichlorobis(di-tert-butylphenylphosphine)palladium(II)
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine