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4,4'-DI-TERT-BUTYLBIPHENYL

4,4'-DI-TERT-BUTYLBIPHENYL ??? ???
?? ??:
1625-91-8
???:
4,4'-DI-TERT-BUTYLBIPHENYL
???(??):
4,4'-Di-tert-butyL;TIMTEC-BB SBB007812;4,4'-DI-T-BUTYLBIPHENYL;4,4'-DI-TERT-BUTYLBIPHENYL;4,4'-Di-t-butylbiphenyl, 99+%;4,4'-Di-tert-butylbiphenyl>4,4'-Di-tert-butylbiphenyl 99%;4,4'-Ditert-butyl-1,1'-biphenyl;4,4'-Di-tert-butylbiphenyl, 99+%;4,4'-Di-tert-butyl-1,1'-biphenyl
CBNumber:
CB8316992
???:
C20H26
??? ??:
266.42
MOL ??:
1625-91-8.mol
MSDS ??:
SDS

4,4'-DI-TERT-BUTYLBIPHENYL ??

???
126-130 °C(lit.)
?? ?
190-192 °C13 mm Hg(lit.)
??
0.9463 (estimate)
???
1.5928 (estimate)
???
190-192°C/13mm
?? ??
Sealed in dry,Room Temperature
???
???: 0.1 g/mL, ??
??? ??
??? ??
??
?? ????? ???-?????
BRN
2095855
CAS ??????
1625-91-8(CAS DataBase Reference)
NIST
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
????? 22-24/25
WGK ?? 3
HS ?? 29029090
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P321 (…) ??? ???.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P362 ??? ??? ?? ?? ?? ?????
NFPA 704
0
0 0

4,4'-DI-TERT-BUTYLBIPHENYL C??? ??, ??, ??

??? ??

Powder

??

It is used in the generation of 1,2-di(lithiomethyl)benzene. It is found to accept electrons from Li metal to give a radical anion which is highly effective in the conversion of alkyl halides to alkyllithiums. 4,4?-Di-tert-butylbiphenyl is used in production of homoallylic amine derivatives. It is also used in the preparation of lithium di-tert-butylbiphenylide, a radical anion, superior to sodium or lithium naphthalenides for metalation reactions. Along with lithium, 4,4?-Di-tert-butylbiphenyl catalyzes; reaction of chloromethyl ethyl ether and different carbonyl compounds to yield corresponding hydroxyethers and reductive opening of N-phenylazetidine.

?? ??

4,4′-Di-tert-butylbiphenyl along with lithium catalyzes:

4,4'-DI-TERT-BUTYLBIPHENYL ?? ?? ? ???

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4,4'-DI-TERT-BUTYLBIPHENYL ?? ??

???( 197)?? ??
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4,4'-DI-TERT-BUTYLBIPHENYL ?? ??:

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