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6018-94-6
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???(??):
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NICKEL OXALATE DIHYDRATE
???(??):
NICKEL OXALATE;NICKEL(II) OXALATE;Diaquaoxalato nickel;Nickel oxalate (solids);NICKEL OXALATE, HYDROUS;NICKEL OXALATE DIHYDRATE;NICKEL(II) OXALATE DIHYDRATE;Nickel (II) oxalate dihydrate≥99.99%;NICKEL(II) OXALATE DIHYDRATE: 99.998%;Nickel(II)oxalatedihydrate(99.998%-Ni)PURATREM
CBNumber:
CB8113357
???:
C2H4NiO6
??? ??:
182.74
MOL ??:
6018-94-6.mol

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insoluble in H2O; soluble in acid solutions,NH2OH 4
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green-white
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Merck
14,6514
Solubility Product Constant (Ksp)
pKsp: 9.4
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NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS ??????
6018-94-6(CAS DataBase Reference)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn,N,T
?? ???? ?? 21/22-20/21/22-50/53-48/23-43-49
????? 24/25-36-9-7-61-60-45-36/37-53
????(UN No.) UN3288
TSCA Yes
?? ?? 6.1
???? III
????(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
H312 ??? ???? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P280,P302+P352, P312, P322, P363,P501
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H350 ?? ??? ? ?? (????? ?? ???? ???? ???? ??? ?? ????? ??? ???? ??) ??? ?? ?? 1A, 1B ?? GHS hazard pictograms
H372 ??? ?? ?? ???? ??(??, ??? ?? ??? ?? ??? ??)? ??? ??? ?? ???? ?? - ?? ?? ?? 1 ?? GHS hazard pictograms P260, P264, P270, P314, P501
H400 ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? GHS hazard pictograms P273, P391, P501
H410 ??? ??? ?? ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? GHS hazard pictograms P273, P391, P501
??????:
P201 ?? ? ?? ???? ?????.
P260 ??·?·??·???·??·...·????? ???? ???.
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P308+P313 ?? ?? ??? ???? ???? ??· ??? ????.
P405 ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
1
3 0

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light green powder(s) . Nickel(II) Oxalate Dihydrate [6018-94-6], Ni(COO)2·2 H2O, Mr 182.76, precipitates as a green powder when oxalic acid or alkali-metal oxalate solutions are added to nickel(II) salt solutions. When heated in vacuum, it evolves water at 150 ℃ and decomposes completely at 300 ℃, giving finely divided nickel suitable for use in catalysis or in the production of nickel carbonyl.

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Nickel oxalate is used for the production of nickel catalysts and magnetic materials.

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Nickel(II) oxalate precipitates as NiC2O4?2H2O when oxalic acid is added to nickel salt solutions. It is isomorphous with the oxalates of magnesium, zinc and iron(II), and has μeff=2.95 BM. When heated in vacuo it decomposes evolving water above 150° and carbon dioxide above 300° leaving finely divided nickel suitable for catalytic purposes or reacting to form the carbonyl. The oxalate dissolves in acids with decomposition and in ammonia with ammine formation.

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Nickel Oxalate is produced as a greenish white crystalline dihydrate.

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