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3-Aminocrotononitrile

3-Aminocrotononitrile ??? ???
?? ??:
1118-61-2
???:
3-Aminocrotononitrile
???(??):
(Z)-3-aMinobut-2-enenitrile;DIACETONITRILE;3-AMINOCROTONITRILE;3-Aminobut-2-enenitrile;3-AMINO-2-BUTENENITRILE;DIONIL;3-Aminocrotonic;3-AMINOCROTONITRIL;β-Aminocrotonitrile;3-IMINOBUTYRONITRILE
CBNumber:
CB7733178
???:
C4H6N2
??? ??:
82.1
MOL ??:
1118-61-2.mol
MSDS ??:
SDS

3-Aminocrotononitrile ??

???
79-81°C
?? ?
120°C 4mm
??
0.952
???
1.4449 (estimate)
???
154°C
?? ??
2-8°C
???
95% ???: ???25mg/mL, ??, ??~???
?? ?? (pKa)
3.88±0.70(Predicted)
??? ??
????
??
???
???
?? ?? ? ?? ???? ? ????.
BRN
1719815
LogP
0.005 (est)
CAS ??????
1118-61-2(CAS DataBase Reference)
NIST
2-Butenenitrile, 3-amino-(1118-61-2)
EPA
2-Butenenitrile, 3-amino- (1118-61-2)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn,T
?? ???? ?? 22-20/21/22-43-24/25
????? 22-24/25-29-36/37-45
????(UN No.) UN 3439 6.1/PG 3
WGK ?? 3
TSCA Yes
???? III
HS ?? 29269090
????(GHS): GHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
H311 ??? ???? ??? ?? ?? ?? - ?? ?? 3 ?? GHS hazard pictograms P280, P302+P352, P312, P322, P361,P363, P405, P501
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
NFPA 704
0
1 0

3-Aminocrotononitrile MSDS


3-Amino-2-butenenitrile

3-Aminocrotononitrile C??? ??, ??, ??

??? ??

Yellowish flakes. 3-Amino-3-methylacrylonitrile [1118-61- 2], b-iminobutyronitrile, b-aminocrotononitrile, diacetonitrile, 3-amino-2-butenenitrile, NCCH=C (NH2) CH3, Mr 82.11, mp (cis-form) 79 – 83℃, mp (trans-form) 52 – 53℃, d774 0.9519, is a yellowish solid soluble in ethanol and diethyl ether; it is sparingly soluble in benzene and water.

??

3-Aminocrotononitrile is used as intermediate for the syntheses of heterocycles (e.g. pyridines and pyrimidines) and for the production of polyurethane). It is used in the pharmaceutical (e.g. production of sulfsomizole) and dyestuff industries. Product Data Sheet

Biochem/physiol Actions

3-Aminocrotononitrile reacts with ferrocenyl-1,2-enones to form ferrocenyl pyridines. It undergoes diazotization coupling reaction with p-substituted anilines to give 2-arylhydrazone-3-ketimino-butyronitriles.

3-Aminocrotononitrile ?? ?? ? ???

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3-Aminocrotononitrile ?? ??

???( 297)?? ??
??? ?? ??? ?? ?? ? ??
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3-Aminocrotononitrile ?? ??:

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