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PHENYL AZIDE

PHENYL AZIDE ??? ???
?? ??:
622-37-7
???:
PHENYL AZIDE
???(??):
Azidobenzene;PHENYL AZIDE;Azido-benzene;triazobenzene;phenylazoimide;Benzene, triazo-;diazobenzeneimide;Phenyl azide solution;Azidobenzene solution;Azidomethane solution - 0.5M solution intert-butyl methyl ether
CBNumber:
CB7390841
???:
C6H5N3
??? ??:
119.12
MOL ??:
622-37-7.mol

PHENYL AZIDE ??

???
-27.5°C
?? ?
212.39°C (rough estimate)
??
1.0860
?? ??
73.5 at 22-24 mm
???
1.5589
???
-12°C
?? ??
-20°C
??? ??
liquid
??
??? ??
BRN
742248
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? F,Xn
?? ???? ?? 11-19-48/20/21/22-38
????? 16
????(UN No.) UN 2398 3 / PGII
WGK ?? 3
????(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H225 ???? ?? ? ?? ??? ?? ?? 2 ?? GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 1 ?? GHS hazard pictograms P280, P305+P351+P338, P310
H373 ??? ?? ?? ???? ??(??, ??? ?? ??? ?? ??? ??)? ??? ??? ? ?? ?? ???? ?? - ?? ?? ?? 2 ?? P260, P314, P501
??????:
P210 ?·???·??·????? ????? - ?? ???.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P314 ???? ??? ???? ??·??? ????.

PHENYL AZIDE C??? ??, ??, ??

??

Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

?? ??

Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.

Safety Profile

Explodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.

PHENYL AZIDE ?? ?? ? ???

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PHENYL AZIDE ?? ??

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