ChemicalBook >?? ???? >?????????????

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?? ??:: 171860-68-7

???:: ?????????????

???(??):: ?????????????

???:: CYCLOPENTYLZINC BROMIDE

???(??):: CYCLOPENTYLZINC BROMIDE;Zinc, bromocyclopentyl-;bromozinc(1+),cyclopentane;cyclopentylzinc(II) broMide;cyclopentylzinc bromide solution;Cyclopentylzinc bromide, 0.50 M in THF;Cyclopentylzinc bromide solution 0.5 in THF;Cyclopentylzinc broMide solution 0.5 M in THF;Cyclopentylzinc broMide, 0.5 M solution in THF, SpcSeal;CYCLOPENTYLZINC BROMIDE, 0.5M SOLUTION I N TETRAHYDROFURAN

CBNumber:: CB6381277

???:: C5H9BrZn

??? ??:: 214.42

MOL ??:: 171860-68-7.mol

?? ?? 32

????????????? ??

??: 0.955 g/mL at 25 °C

???: 1 °F

?? ??: 2-8°C

???: ?? ?????.

??: Air Sensitive

?? ??: ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

?? ? ?? ??
?? ? ???? ?? (GHS)

??? ??	F,Xn
?? ???? ??	11-14-19-22-36/37/38-40-36/37
?????	16-26-33-36-36/37
????(UN No.)	UN 3399 4.3/PG 2
WGK ??	1
?? ??	4.3
HS ??	29319090

????(GHS):

?? ?:

Danger

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H225	???? ?? ? ??	??? ??	?? 2	??	P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261	?? ??? ?????? ????	???? ?? ? ???	?? 2 ?? 3	?? ??	P231+P232, P280, P370+P378,P402+P404, P501
H302	??? ???	?? ?? ?? - ??	?? 4	??	P264, P270, P301+P312, P330, P501
H314	??? ?? ??? ?? ??? ???	????? ?? ?????	?? 1A, B, C	??	P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315	??? ??? ???	????? ?? ?????	?? 2	??	P264, P280, P302+P352, P321,P332+P313, P362
H318	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 1	??	P280, P305+P351+P338, P310
H319	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 2A	??	P264, P280, P305+P351+P338,P337+P313P
H333	???? ??? ? ??	?? ?? ?? ??	?? 5		P304+P312
H335	?? ???? ??? ? ??	?? ???? ?? - 1? ??;???? ??	?? 3	??
H351	?? ??? ??? ??? (????? ?? ???? ???? ???? ??? ?? ????? ??? ???? ??)	??? ??	?? 2	??	P201, P202, P281, P308+P313, P405,P501

??????:

P210	?·???·??·????? ????? - ?? ???.
P223	?? ???? ???.
P231+P232	??? ?? ??? ????, ??? ?????.
P280	????/???/???/?????? ?????.
P303+P361+P353	??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338	?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P370+P378	?? ? ?? ?? ?? (Section 5. ??, ??? ????? ??? ???)?(?) ?????.
P402+P404	??? ??? ?????. ??? ??? ?????.
P403+P235	??? ? ?? ?? ???? ???? ?????.
P405	???? ?????.

NFPA 704

	3
3		2
	W

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Cyclopentylzinc bromide is an organozinc reagent that can be used in:

The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.

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???	??	???	??	?? ?	??
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????????????? ?? ??:

4-BROMOPHENYLZINC IODIDE 5-METHYL-2-PYRIDYLZINC BROMIDE 2-THIENYLZINC BROMIDE 3-METHYL-2-PYRIDYLZINC BROMIDE 2-TERT-BUTOXY-2-OXOETHYLZINC CHLORIDE 4-METHYL-2-PYRIDYLZINC BROMIDE PHENETHYLZINC BROMIDE 2,4-DIFLUOROBENZYLZINC BROMIDE Zinc, bromo-2-propenyl- 2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T& 2-BUTYLZINC BROMIDE 1-METHYLBUTYLZINC BROMIDE CYCLOPENTYLZINC BROMIDE 1-ETHYLPROPYLZINC BROMIDE EXO-2-NORBORNYLZINC BROMIDE BUTYLZINC BROMIDE 1-PENTYLZINC BROMIDE N-PROPYLZINC BROMIDE

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