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3,4-Dihydroxybenzophenone

3,4-Dihydroxybenzophenone ??? ???
?? ??:
10425-11-3
???:
3,4-Dihydroxybenzophenone
???(??):
3,4-Dihydroxybenzoph;4-Benzoylpyrocatechol;3,4-dihydroxybenophenone;4-benzoylbenzene-1,2-diol;3,4-dihydroxybnezophenone;3,4-DIHYDROXYBENZOPHENONE;3,4-dihydroxy benzophonone;3,4-Dihydroxybenzophenone>3,4-DIHYDROXY-DIPHENYL KETONE;3,4-Dihydroxybenzophenone 97%
CBNumber:
CB6213367
???:
C13H10O3
??? ??:
214.22
MOL ??:
10425-11-3.mol

3,4-Dihydroxybenzophenone ??

???
144-148 °C (lit.)
?? ?
314.35°C (rough estimate)
??
1.1956 (rough estimate)
???
1.5090 (estimate)
?? ??
Inert atmosphere,Room Temperature
???
???? ???
??? ??
powder to crystal
?? ?? (pKa)
8.02±0.18(Predicted)
??
White to Light yellow to Green
InChIKey
ARWCZKJISXFBGI-UHFFFAOYSA-N
CAS ??????
10425-11-3(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36-37/39
WGK ?? 3
HS ?? 29145090
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P405 ???? ?????.
NFPA 704
1
2 0

3,4-Dihydroxybenzophenone C??? ??, ??, ??

??? ??

cream crystalline powder

?? ??

Preparation by Fries rearrangement of pyrocatechol dibenzoate,
in the presence of aluminium chloride in nitrobenzene ? at 100° for 4 h (quantitative yield) or heated on a steam bath for 6 h ];
? in the presence of Nafion-XR, a H+-form ion exchange resin, at 175° for 4 h under nitrogen (38%).

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 2601, 1994 DOI: 10.1016/S0040-4039(00)77182-6

3,4-Dihydroxybenzophenone ?? ?? ? ???

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?? ??


3,4-Dihydroxybenzophenone ?? ??

???( 290)?? ??
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3,4-Dihydroxybenzophenone ?? ??:

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