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2-(Trimethylsilylmethyl)allyl acetate

2-(Trimethylsilylmethyl)allyl acetate ??? ???
?? ??:
72047-94-0
???:
2-(Trimethylsilylmethyl)allyl acetate
???(??):
2-[(TRIMETHYLSILYL)METHYL]-2-PROPEN-1-YL ACETATE;DK875;SKL104;2-(Acetoxymethyl)allyltrimethyliane;2-(ACETOXYMETHYL)ALLYTRIMETHYLSILANE;2-(TRIMETHYLSILYLMETHYL)ALLYL ACETATE;(2-(Ethoxymethyl)allyl)trimethylsilane;[2-(ACETOXYMETHYL)ALLYL]TRIMETHYLSILANE;2-((trimethylsilyl)methyl)-2-propen-1-yl;2-(Trimethylsilylmethyl)allyl acetate,98%
CBNumber:
CB5245853
???:
C9H18O2Si
??? ??:
186.32
MOL ??:
72047-94-0.mol
MSDS ??:
SDS

2-(Trimethylsilylmethyl)allyl acetate ??

?? ?
95 °C7 mm Hg(lit.)
??
0.877 g/mL at 25 °C(lit.)
???
n20/D 1.440(lit.)
???
160 °F
?? ??
Inert atmosphere,2-8°C
???
??? ???? ????.
??? ??
??
??
???
???
?? ??
BRN
1933657
InChIKey
IKQWABMHZKGCLX-UHFFFAOYSA-N
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38-14
????? 26-36/37/39-37/39
WGK ?? 3
HS ?? 29319090
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

2-(Trimethylsilylmethyl)allyl acetate C??? ??, ??, ??

??? ??

Clear colorless liquid

??? ??

bp 68–70°C/6.5 mmHg;60–61°C/2.5 mmHg.

??

precursor for palladium trimethylenemethane cycloaddition reactions.

?? ??

commercially available but expensive. Several preparations of (1) or the precursor alcohol (2) have been reported. The simplest involves the direct silylation of methallyl alcohol (eq 1).
72047-94-0 synthesis

2-(Trimethylsilylmethyl)allyl acetate ?? ?? ? ???

???

?? ??


2-(Trimethylsilylmethyl)allyl acetate ?? ??

???( 115)?? ??
??? ?? ??? ?? ?? ? ??
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2-(Trimethylsilylmethyl)allyl acetate ?? ??:

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