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598-31-2
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???(??):
??????;????????;???-2-????;1-???-2-????;1-??????-2-?;2-????, 1-???-;?????;????????;???-2-????;?????????;???, ???-;???? ?????;?????????;??-??????
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BROMOACETONE
???(??):
CH3COCH2Br;Bromopropanone;B-Stoff;Martonite;BROMOACETONE;1-Bromoacetone;acetonylbromide;bromo-2-propanon;Monobromoacetone;Acetonyl bromide
CBNumber:
CB4301956
???:
C3H5BrO
??? ??:
136.98
MOL ??:
598-31-2.mol
MSDS ??:
SDS

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-36,5°C
?? ?
137°C
??
1,63 g/cm3
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nD15 1.4697
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51℃
Specific Gravity
1.63 (0℃)
CAS ??????
598-31-2(CAS DataBase Reference)
NIST
2-Propanone, 1-bromo-(598-31-2)
EPA
Bromoacetone (598-31-2)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
?? ???? ?? 11-23/24/25-34
????? 26-36/37/39
????(UN No.) 1569
?? ?? 6.1(a)
???? II
HS ?? 29147000
?? ?? ??? 598-31-2(Hazardous Substances Data)
???? ?? KE-05-0239
?????? ??? 97-1-109
?? ? ???? ????: ????; ???(??)????: ???-2-???? ? ?? 1% ?? ??? ???
????(GHS): GHS hazard pictograms
?? ?: Warning
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H226 ??? ?? ? ?? ??? ?? ?? 3 ??
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Colorless liquid when pure, rapidly becomes violet even in absence of air. Soluble in ace- tone, alcohol, benzene, and ether; slightly soluble in water.

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Chemical war gas.

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ChEBI: An alpha-bromoketone that is acetone in which one of the hydrogens is replaced by a bromine atom. A poweful lachrymator, it was formerly used as a chemical weapon.

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A clear colorless liquid turning violet on standing, even in the absence of air, and decomposing to a black resinous mass on long standing. Denser than water and poorly soluble in water. Hence sinks in water. A violent lachrymator--low concentrations are very irritating to the eyes; high concentrations or prolonged exposure at lower concentrations may have adverse health effects. Very toxic by inhalation. Contact with the liquid causes painful burns. Used as a chemical war gas.

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Highly flammable. Soluble in water.

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BROMOACETONE decomposes on standing.

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Toxic by inhalation and skin contact. A lachrymator gas, strong irritant.

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Very powerful lachrymator and upper respiratory tract irritant. Intensely irritating to the eyes, nose, throat, and lungs. Corrosive to the skin.

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Special Hazards of Combustion Products: Toxic fumes of Bromine

Safety Profile

A poisonous gas. Moderately toxic to humans by inhalation. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.

Purification Methods

Stand bromoacetone over anhydrous CaCO3, filter, distil it under low vacuum, and store it with CaCO3 in the dark at 0o. [Levene Org Synth Coll Vol II 88 1943.] Violently LACHRYMATORY and skin IRRITANT.

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