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3-IODO-2-????????-1-???

3-IODO-2-????????-1-???
3-IODO-2-????????-1-??? ??? ???
?? ??:
80121-73-9
???:
3-IODO-2-????????-1-???
???(??):
3-IODO-2-????????-1-???
???:
3-IODO-2-TRIMETHYLSILYLMETHYL-1-PROPENE
???(??):
3-IODO-2-TRIMETHYLSILYLMETHYL-1-PROPENE;Silane, [2-(iodomethyl)-2-propen-1-yl]trimethyl-
CBNumber:
CB42582465
???:
C7H15ISi
??? ??:
254.18
MOL ??:
80121-73-9.mol

3-IODO-2-????????-1-??? ??

?? ?
185.6±28.0 °C(Predicted)
??
1.313±0.06 g/cm3(Predicted)
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3-IODO-2-????????-1-??? C??? ??, ??, ??

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bp 25 °C/0.5 mmHg.

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3-Iodo-2-trimethylsilylmethyl-1-propene is widely used as a bifunctional conjunctive reagent that serves as a dipolar trimethylenemethane synthon; treatment with SnF2 affords a dianionic trimethylenemethane synthon.The most common use of this reagent is as a 1,3-dipolar synthon for trimethylenemethane (TMM).

?? ??

From the corresponding mesylate upon treatment with sodium iodide in acetone. The mesylate can be prepared from the commercially available alcohol.

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3-Iodo-2-trimethylsilylmethyl-1-propene can be stored in the dark at -20 °C for up to 3 months without significant deterioration.

3-IODO-2-????????-1-??? ?? ?? ? ???

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3-IODO-2-????????-1-??? ?? ??

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