ChemicalBook >?? ???? >?? ??>?? ??>?? ?? ? ?? ???>?? ?, ? ?? ? ???>N-(tert-???????)-(S)-(+)-3-?????

N-(tert-???????)-(S)-(+)-3-?????

N-(tert-???????)-(S)-(+)-3-????? ??? ???

?? ??:: 101469-92-5

???:: N-(tert-???????)-(S)-(+)-3-?????

???(??):: N-(tert-???????)-(S)-(+)-3-?????

???:: N-(tert-Butoxycarbonyl)-(S)-(+)-3-pyrrolidinol

???(??):: tert-butyl (S)-3-hydroxypyrrolidine-1-carboxylate;(S)-1-BOC-3-HYDROXYPYRROLIDINE;(S)-TERT-BUTYL 3-HYDROXYPYRROLIDINE-1-CARBOXYLATE;(S)-N-BOC-3-PYRROLIDINOL;(S)-1-N-Boc-3-pyrrolidinol;(S)-N-BOC-3-HYDROXYPYRROLIDINE;(S)-1-Boc-3;(S)-1-BOC-3-Pyrolidinol;Cilnidipine Impurity 62;(S)-1-BOC-3-PYRROLIDINOL

CBNumber:: CB4232377

???:: C9H17NO3

??? ??:: 187.24

MOL ??:: 101469-92-5.mol

MSDS ??:: SDS

?? ?? 398

N-(tert-???????)-(S)-(+)-3-????? ??

???: 60-64 °C (lit.)

?? ?: 273.3±33.0 °C(Predicted)

??: 26 º (c=1%, MeOH)

??: 1.142±0.06 g/cm3(Predicted)

???: 27 ° (C=1, MeOH)

?? ??: Keep in dark place,Sealed in dry,Room Temperature

???: ???? ???

?? ?? (pKa): 14.74±0.20(Predicted)

??? ??: ??? ??

??: ???? ?? ???

optical activity: [α]20/D +26°, c = 1% in methanol

BRN: 6271108

InChIKey: APCBTRDHCDOPNY-ZETCQYMHSA-N

CAS ??????: 101469-92-5(CAS DataBase Reference)

?? ? ?? ??
?? ? ???? ?? (GHS)

??? ??	T,Xi
?? ???? ??	25-37/38-41-R41-R37/38-R25
?????	26-39-45-S45-S39-S26
????(UN No.)	UN 2811 6.1/PG 3
WGK ??	3
F ??????	10
?? ??	6.1
????	Ⅲ
HS ??	29339900

????(GHS):

?? ?:

Danger

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H301	??? ???	?? ?? ?? - ??	?? 3	??	P264, P270, P301+P310, P321, P330,P405, P501
H315	??? ??? ???	????? ?? ?????	?? 2	??	P264, P280, P302+P352, P321,P332+P313, P362
H318	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 1	??	P280, P305+P351+P338, P310
H335	?? ???? ??? ? ??	?? ???? ?? - 1? ??;???? ??	?? 3	??

??????:

P280	????/???/???/?????? ?????.
P302+P352	??? ??? ??? ?? ????.

NFPA 704

	1
2		0

N-(tert-???????)-(S)-(+)-3-????? C??? ??, ??, ??

??? ??

white to light yellow crystal powde

??

(S)-(+)-N-Boc-3-pyrrolidinol can be used as a reactant to synthesize:

tert-Butyl 3-(2-bromophenoxy)pyrrolidine-1-carboxylate, which is employed as a key intermediate in the preparation of IkB-kinase IKK2 inhibitor.
Dimethoxy-pyrrolidylquinazoline , and peptidomimetic quinoline derivatives.

N-(tert-???????)-(S)-(+)-3-????? ?? ?? ? ???

???

?? ??

??2-???-4-???-?????? (S)-1-Boc-3-???????-???? (R)-1-Boc-3-??????? (S)-tert-butyl 3-isopropoxypyrrolidine-1-carboxylate 1-Pyrrolidinecarboxylic acid, 3-(2-bromo-5-chlorophenoxy)-, 1,1-dimethylethyl ester, (3S)- (S)-1-(TERT-BUTOXYCARBONYL)PIPERIDIN-3-YL??????? (S)-3-Hydroxypyrrolidine hydrochloride

N-(tert-???????)-(S)-(+)-3-????? ?? ??

???( 398)?? ??

???	??	???	??	?? ?	??
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N-(tert-???????)-(S)-(+)-3-????? ?? ??:

N-Boc-cis-4-Hydroxy-L-proline (2R,4R)-N-Boc-4-hydroxypyrrolidine-2-carboxylic acid N-(tert-Butoxycarbonyl)-(S)-(+)-3-pyrrolidinol (3R,4R)-tert-Butyl 3-amino-4-hydroxypyrrolidine-1-carboxylate N-Boc-cis-4-Hydroxy-L-proline methyl ester (R)-1-Boc-3-hydroxypyrrolidine 1-(tert-Butoxycarbonyl)-3-pyrrolidinol 3-Pyrrolidinol DL-3-PYRROLIDINOL (2S,4S)-1-(TERT-BUTOXYCARBONYL)-4-(2-NAPHTHYLOXY)-2-PYRROLIDINECARBOXYLIC ACID BOC-4-HYDROXY-L-PYRROLIDINE LACTONE BOC-(2S,3S)-3-HYDROXYPYRROLIDINE-2-CARBOXYLIC ACID BOC-CIS-3-HYDROXY-D-PROLINE (2S,4S)-1-(TERT-BUTOXYCARBONYL)-4-PHENOXY-2-PYRROLIDINECARBOXYLIC ACID BOC-D-HYP-OTBU BOC-CISHYP(BZL)-OH (2S,4S)-1-(TERT-BUTOXYCARBONYL)-4-(2-CHLORO-4-FLUOROPHENOXY)-2-PYRROLIDINECARBOXYLIC ACID (2S,4S)-1-(TERT-BUTOXYCARBONYL)-4-(4-CHLORO-2-FLUOROPHENOXY)-2-PYRROLIDINECARBOXYLIC ACID

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