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Tris(trimethylsilyl) borate

Tris(trimethylsilyl) borate ??? ???
?? ??:
4325-85-3
???:
Tris(trimethylsilyl) borate
???(??):
TMSB;Tris(trimethylsiloxy)boron, min. 97%;BORON TRIMETHYLSILOXIDE;TRIS(TRIMETHYSILOXY)BORON;TRIS(TRIMETHYLSILOXY)BORON;TRIS(TRIMETHYLSILYL) BORATE;Borane, tris(trimethylsiloxy)-;TRIS(TRIMETHYLSILOXY)BORON 97+%;TRIS(TRIMETHYLSILYL) BORATE 99%;Tris(trimethylsiloxy)boron ,96%
CBNumber:
CB3733453
???:
C9H27BO3Si3
??? ??:
278.38
MOL ??:
4325-85-3.mol
MSDS ??:
SDS

Tris(trimethylsilyl) borate ??

???
-35°C
?? ?
186 °C (lit.)
??
0.831 g/mL at 25 °C (lit.)
???
n20/D 1.386(lit.)
???
109 °F
?? ??
Inert atmosphere,2-8°C
??? ??
??
Specific Gravity
0.828
??
???
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
??
Moisture Sensitive
BRN
1772733
InChI
InChI=1S/C9H27BO3Si3/c1-14(2,3)11-10(12-15(4,5)6)13-16(7,8)9/h1-9H3
InChIKey
YZYKZHPNRDIPFA-UHFFFAOYSA-N
SMILES
[Si](C)(C)(C)OB(O[Si](C)(C)C)O[Si](C)(C)C
CAS ??????
4325-85-3
EPA
Silanol, trimethyl-, triester with boric acid (H3BO3) (4325-85-3)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 10-36/37/38
????? 26-36
????(UN No.) UN 1993 3/PG 3
WGK ?? 3
F ?????? 10-21
TSCA Yes
?? ?? 3
???? III
HS ?? 29319090
???? ?? 2014-3-6028
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H226 ??? ?? ? ?? ??? ?? ?? 3 ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P210 ?·???·??·????? ????? - ?? ???.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
2
2 1

Tris(trimethylsilyl) borate C??? ??, ??, ??

??? ??

Clear colorless liquid

??

Tris(trimethylsilyl) borate is used as intermediate of organic synthesis and additive of lithium battery electrolyte.

?? ??

[1] Yan Chunfeng . “Tris(trimethylsilyl) borate as an electrolyte additive for high-voltage lithium-ion batteries using LiNi1/3Mn1/3Co1/3O2 cathode.” Journal of Energy Chemistry 25 4 (2016): Pages 659-666.
[2] Jie Wang . “Adjusting the solvation structure with tris(trimethylsilyl)borate additive to improve the performance of LNCM half cells.”Journal of Energy Chemistry 67 (2022): Pages 55-64.

Tris(trimethylsilyl) borate ?? ?? ? ???

???

?? ??

2-Pyridineboronic acid 3-Quinolineboronic acid 6-METHYLPYRIDINE-2-BORONIC ACID Bis(trimethylsilyl)sulfate

Tris(trimethylsilyl) borate ?? ??

???( 255)?? ??
??? ?? ??? ?? ?? ? ??
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Tris(trimethylsilyl) borate ?? ??:

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