Acetylferrocene
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Acetylferrocene ??
- ???
- 81-83 °C (lit.)
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- 160-163 °C (3.0004 mmHg)
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- >1 g/cm3 (20℃)
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- 160-163°C/4mm
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- Sealed in dry,Room Temperature
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- ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
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- CAS ??????
- 1271-55-2(CAS DataBase Reference)
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| ??? ?? | T+ | ||
|---|---|---|---|
| ?? ???? ?? | 28 | ||
| ????? | 28-36/37-45-28A-1 | ||
| ????(UN No.) | UN 2811 6.1/PG 2 | ||
| WGK ?? | 3 | ||
| RTECS ?? | OB3700000 | ||
| F ?????? | 10 | ||
| TSCA | Yes | ||
| ?? ?? | 6.1 | ||
| ???? | II | ||
| HS ?? | 29310095 | ||
| ?? | LDLo orl-rat: 5 mg/kg EPASR* 8EHQ-1285-0578 |
Acetylferrocene C??? ??, ??, ??
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orange crystalline powder??
1-Acetylferrocene was originally used in military or space field as an additive in rocket propellant, to promote the burning rate. Its ferrocenyl derivative has wide applications to biological and medical fields such as ferrocene-modified beta-lactam because of its physiological activity of anti-malarial, anti-tumor, bactericidal, anti-inflammatory, treatment of anemia, inhibition of enzymatic activity and so on by virtue of its unique structure and diverse properties.Safety Profile
Poison by ocular and intravenous routes. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes.Purification Methods
Orange-red crystals are obtained when it is recrystallised from isooctane or *C6H6, and then sublimed at 100o/1mm. The oxime has m 167-170o (from Et2O or aqueous EtOH). The semicarbazone has m 198-201o (from EtOH). [Richmond & Freiser J Am Chem Soc 77 2022 1955, Weinmayer J Am Chem Soc 77 3009 1955, Broadhead et al. J Chem Soc 650 1958, Beilstein 16 IV 1798.]Acetylferrocene ?? ?? ? ???
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Acetylferrocene ?? ??
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| ??? | ?? | ??? | ?? | ?? ? | ?? |
|---|---|---|---|---|---|
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| Nanjing Finetech Chemical Co., Ltd. | 025-85710122 17714198479 |
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| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
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Acetylferrocene ?? ??:
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Diethyl acetylmalonate
ACETYLPHOSPHONIC ACID DIETHYL ESTER
4'-Methoxyacetoacetanilide
Aminoferrocene
Ethylferrocene
Vinylferrocene
tert-Butylferrocene
ETHYNYLFERROCENE
1,1'-Diacetylferrocene
1,1'-DIBENZOYLFERROCENE
3-FERROCENOYLPROPIONIC ACID
Benzoylferrocene
Butyrylferrocene
Propionylferrocene