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N-(?????)-N-(????????)????

N-(?????)-N-(????????)????
N-(?????)-N-(????????)???? ??? ???
?? ??:
93102-05-7
???:
N-(?????)-N-(????????)????
???(??):
N-(?????)-N-(????????)????
???:
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
???(??):
N-benzyl-1-methoxy-N-((trimethylsilyl)methyl)methanamine;N-(MethoxyMethyl)-1-phenyl-N-(triMethylsilylMethyl)MethanaMine;N-benzyl(methoxy)-N-((trimethylsilyl)methyl)methanamine;)-N-trimethyL;cas:93102-05-7;-N-(methoxymethyL;N-(Methoxymethyl)-N-(trimethyl;N-(Methoxymethyl)-N-(trimethylsilyl) benzylamine;Benzyl-methoxymethyl-trimethylsilanylmethylamine;N-Benzyl-N-methoxymethyltrimethylsilylmethanamine
CBNumber:
CB2715045
???:
C13H23NOSi
??? ??:
237.41
MOL ??:
93102-05-7.mol
MSDS ??:
SDS

N-(?????)-N-(????????)???? ??

?? ?
76 °C0.3 mm Hg(lit.)
??
0.928 g/mL at 25 °C(lit.)
???
n20/D 1.492(lit.)
???
151 °F
?? ??
Keep in dark place,Sealed in dry,Room Temperature
???
?????, ???????? ?????.
??? ??
??
?? ?? (pKa)
7.29±0.50(Predicted)
??
????~???
Specific Gravity
0.928
??
Moisture & Light Sensitive
Hydrolytic Sensitivity
2: reacts with aqueous acid
BRN
4311216
InChIKey
RPZAAFUKDPKTKP-UHFFFAOYSA-N
CAS ??????
93102-05-7(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-37/39
????(UN No.) 1993
WGK ?? 3
?? ?? 3
???? Ⅲ
HS ?? 29319090
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
2 0

N-(?????)-N-(????????)???? MSDS


N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamine

N-(?????)-N-(????????)???? C??? ??, ??, ??

??? ??

N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine is clear colorless to light yellow liquid

??? ??

bp 77–80°C/0.5 mmHg.

??

N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine is useful reagent in synthesizing N-benzyl substituted pyrrolidines by [3+2] cycloaddition to α,ßunsaturated esters.

?? ??

most conveniently prepared by treatment of benzylamine with chloromethyltrimethylsilane followed by formaldehyde and methanol.Access to higher ether homologs is achieved by replacing methanol with the appropriate alcohol. An alternate procedure involves alkylation of lithium N-benzyltrimethylsilymethylamide with methoxymethyl chloride.

N-(?????)-N-(????????)???? ?? ?? ? ???

???

???? ???? ??????????? ???? ??????

?? ??

CIS-5-BENZYLTETRAHYDROPYRROLO[3,4-C]PYRROLE-1,3(2H,3AH)-DIONE 1-??-3-????????-????-3-????? ??1-??-4,4-???????-3-??????? 3,4-Pyrrolidinedicarboxylic acid, 1-(phenylmethyl)-, 3,4-dimethyl ester, (3S,4S)- 2-??-??????-??????[C]PYRROL-4-ONE Methyl DL-1-benzyl-4-phenylpyrrolidine-3-carboxylate

N-(?????)-N-(????????)???? ?? ??

???( 355)?? ??
??? ?? ??? ?? ?? ? ??
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N-(?????)-N-(????????)???? ?? ??:

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