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S-TERT-BUTYL ACETOTHIOACETATE

S-TERT-BUTYL ACETOTHIOACETATE ??? ???
?? ??:
15925-47-0
???:
S-TERT-BUTYL ACETOTHIOACETATE
???(??):
tert-Butyl acetothiolacetate;S-TERT-BUTYL ACETOTHIOACETATE;S-tert-Butyl thioacetoacetate;S-tert-Butyl 3-oxothiobutyrate;S-(tert-Butyl) 3-oxobutanethioate;Acetyl(tert-butylthiocarbonyl)methane;3-Oxothiobutyric acid S-tert-butyl ester;3-Oxobutanethioic acid S-tert-butyl ester;3-Oxo-butanethioic acid S-tert-butyl ester;Acetoacetic acid, 1-thio-, S-tert-butyl ester
CBNumber:
CB2407913
???:
C8H14O2S
??? ??:
174.26
MOL ??:
15925-47-0.mol

S-TERT-BUTYL ACETOTHIOACETATE ??

?? ?
95-100 °C0.9 mm Hg(lit.)
??
0.994 g/mL at 25 °C(lit.)
???
n20/D 1.486(lit.)
???
182 °F
?? ?? (pKa)
8.90±0.46(Predicted)
LogP
1.672 (est)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36/37/39
WGK ?? 3
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P321 (…) ??? ???.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P362 ??? ??? ?? ?? ?? ?????

S-TERT-BUTYL ACETOTHIOACETATE C??? ??, ??, ??

Synthesis Reference(s)

Synthetic Communications, 22, p. 2329, 1992 DOI: 10.1080/00397919208019087

S-TERT-BUTYL ACETOTHIOACETATE ?? ?? ? ???

???

?? ??

????? 2,5-???????? N-(2-?????)-3-???????

S-TERT-BUTYL ACETOTHIOACETATE ?? ??

???( 24)?? ??
??? ?? ??? ?? ?? ? ??
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S-TERT-BUTYL ACETOTHIOACETATE ?? ??:

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