Bis(2,2,2-trichloroethyl) azodicarboxylate has been used:
in the asymmetric synthesis of substituted cycloalkyl[b]indoles
as amination reagent during the aza-ene reaction of different alkenes to yield the corresponding allyl amines
in para-directed amination of C2-alkyl substituted anisole
in the synthesis of acid- and base-sensitive azo compounds and in Diels-Alder cycloadditions
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Thermal inverse-type hetero-Diels-Alder reaction of O-silyl-protected lactal and bis(2,2,2-trichloroethyl) azodicarboxylate has been reported.
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Bis(2,2,2-trichloroethyl) azodicarboxylate is same as with all azo compounds, caution should be exercised to avoid
exposure of the material to heat. Store in a brown bottle.
