Dicyclohexylborane
Dicyclohexylborane ??
???
103-105 °C
?? ?
263.7±23.0 °C(Predicted)
???
Soluble in THF, diethyl ether, dichloromethane, and pentane.
??
?? ? ?? ??
?? ? ???? ?? (GHS)
????(GHS):
?? ?:
Danger
??·?? ??:
??
??·?? ??
?? ??
??
?? ?
?? ??
P- ??
H250
??? ???? ??? ???
????? ??;????? ??
?? 1
??
P210, P222, P280, P302+P334,P370+P378, P422
H314
??? ?? ??? ?? ??? ???
????? ?? ?????
?? 1A, B, C
??
P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P210
?·???·??·????? ????? - ?? ???.
P222
??? ???? ???.
P260
??·?·??·???·??·...·????? ???? ???.
P264
?? ??? ?? ??? ????.
P264
?? ??? ?? ??? ????.
P280
????/???/???/?????? ?????.
P301+P330+P331
???? ?? ?????. ??? ?? ?? ???.
P302+P334
??? ?? ??,??? ???/?? ??? ???
P303+P361+P353
??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P304+P340
???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338
?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P310
?? ????(??)? ??? ????.
???? ?? ????(??)? ??? ????.
P321
(…) ??? ???.
P363
?? ??? ??? ??? ?????.
P370+P378
?? ? ?? ?? ?? (Section 5. ??, ??? ????? ??? ???)?(?) ?????.
P405
???? ?????.
P422
??? ???(?) ???? ?????.
P501
...? ??? / ??? ?? ???.
Dicyclohexylborane C??? ??, ??, ??
Synthesis Reference(s)
Journal of the American Chemical Society, 95, p. 6876, 1973
DOI: 10.1021/ja00801a081
Synthesis
Dicyclohexylborane is a stable white solid available via the hydroboration of cyclohexene with either Borane-Tetrahydrofuran or Borane-Dimethyl Sulfide. Recently, dicyclohexylborane has been prepared via the hydroboration of cyclohexene with borane-1,4-thioxane.
Dicyclohexylborane ?? ?? ? ???
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?? ??
Dicyclohexylborane ?? ??
???( 26)?? ??
China 24
Germany 1
United States 1
Global 26