BENZYLIDENEMALONONITRILE
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BENZYLIDENEMALONONITRILE ??
- ???
- 83-85 °C (lit.)
- ?? ?
- 120-125°C 0,6mm
- ??
- 1.1975 (rough estimate)
- ???
- 1.4820 (estimate)
- ???
- 120-125°C/0.6mm
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- Sealed in dry,Room Temperature
- ???
- ???? ???
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- powder to crystal
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- White to Orange to Green
- BRN
- 1907519
- CAS ??????
- 2700-22-3(CAS DataBase Reference)
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- ?? ? ???? ?? (GHS)
??? ?? | Xn | ||
---|---|---|---|
?? ???? ?? | 20/21/22-36/37/38 | ||
????? | 26-36/37/39 | ||
????(UN No.) | 3276 | ||
WGK ?? | 3 | ||
RTECS ?? | OO3500000 | ||
?? ?? | 6.1 | ||
???? | III | ||
HS ?? | 29269095 |
BENZYLIDENEMALONONITRILE C??? ??, ??, ??
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SLIGHTLY YELLOW NEEDLE-LIKE CRYSTALLINE POWDER??
Benzylidenemalononitrile was used in fluorescence-based assay for determination of soluble methane monooxygenase activity in solution.?? ??
Benzylidenemalononitrile undergoes rapid and catalyst-free solid/vapor reaction with primary alkyl amines to yield N-benzylidene-amine. It undergoes addition reaction with octyl- and decylzirconocene chloride. It is a potential substrate for soluble methane monooxygenase.Purification Methods
Recrystallise the nitrile from EtOH [Bernasconi et al. J Am Chem Soc 107 3612 1985]. It has max at 307nm (EtOH). [Beilstein 9 H 895, 9 II 640, 9 III 4380, 9 IV 3462.]BENZYLIDENEMALONONITRILE ?? ?? ? ???
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ZEAUJQWDPKRESH-SDNWHVSQSA-N
Benzene, (2,2-dinitroethenyl)-
Benzenemethanamine, N-(phenyl-13C)- (9CI)
2-amino-7-hydroxy-4-phenyl-4H-chromene-3-carbonitrile
3-amino-1-phenyl-1H-benzo[f]chromene-2-carbonitrile
14H-Dibenzo[a,j]xanthene, 14-phenyl-
2-??-1,3-?????
N-???????
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2-???
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BENZYLIDENEMALONONITRILE ?? ??
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??? | ?? | ??? | ?? | ?? ? | ?? |
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BENZYLIDENEMALONONITRILE ?? ??:
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TYRPHOSTIN A1
9-DICYANOMETHYLENE-2,4,7-TRINITROFLUORENE
BENZYLIDENEMALONONITRILE
4-HYDROXYBENZYLIDENEMALONONITRILE
TYRPHOSTIN A25
AG 18
2-(4-Acetamidobenzylidene)malononitrile
3,5-DI-T-BUTYL-4-HYDROXY-BENZYLIDENEMALONONITRILE
2-Methyl-4-[N-ethyl-N-[2-(phenylcarbamoyloxy)ethyl]amino]benzylidenemalononitrile
9-(DICYANOMETHYLENE)FLUORENE
2-(4-TRIFLUOROBENZYLIDENE)-MALONONITRILE
2-(4-METHYLBENZYLIDENE)-MALONONITRILE
2-[1-(4-CHLOROPHENYL)ETHYLIDENE]MALONONITRILE
(BENZO[3,4-D]1,3-DIOXOLAN-5-YLMETHYLENE)METHANE-1,1-DICARBONITRILE
2-CHLORO-6-FLUOROBENZALMALONONITRILE
ALPHA-CHLOROBENZYLIDENEMALONONITRILE