5,6-ジヒドロ-2-メチル-N-フェニル-1,4-オキサチイン-3-カルボアミド 化學特性,用途語,生産方法
外観
白色, 結(jié)晶?粉末又は塊
溶解性
水199mg/l(25℃)。アセトン177、ジクロロメタン353、メタノール88、酢酸エチル93 mg/l(25℃)エタノール及びアセトンに溶け、水にほとんど溶けない。
用途
ミトコンドリア複合體Ⅱ阻害剤ムギ類の裸黒穂病
農(nóng)薬用途
殺菌剤
化學的特性
Carboxin is a white crystalline solid
使用
Carboxine is an fungicide used for the control of fruit rot of custard apple.
定義
ChEBI: An anilide obtained by formal condensation of the amino group of aniline with the carboxy group of 2-methyl-5,6-dihydro-1,4-oxathiine-3-carboxylic acid. A fungicide for control of bunts and smuts normally that is normally used as a seed treatment.
一般的な説明
Off-white crystals. Systemic fungicide and seed protectant.
作用機制
複合體Ⅱ（コハク酸脫水素酵素）を阻害
農(nóng)業(yè)用途
Fungicide: Carboxin is a General Use Pesticide (GUP) and is used as a seed protectant. It is often used in combination with other fungicides such as thiram or captan. Carboxin is a systemic anilide fungicide. It is used as a seed treatment for control of smut, rot, and blight on barley, oats, rice, cotton, vegetables, corn and wheat. It is also used to control fairy rings on turf grass. Carboxin may be used to prevent the formation of these diseases or may be used to cure existing plant diseases. Also used as a wood preservative.
製品名
CADAN®; CARBOXIN OXATHION PESTICIDE®; CASWELL No. 165 A®; D-735®; F-735®; FLO PRO V SEED PROTECTANT®[C]; KEMIKAR®; OXALIN®; PADAN®; SANVEX®; THIOBEL®; VEGETOX®; VITAFLO®; VITAVAX® 200FF; V 4X®
安全性プロファイル
Poison by ingestion.
Moderately toxic by skin contact and
possibly other routes. Mutation data
reported. When heated to decomposition it
emits very toxic fumes of NOx and SOx.
職業(yè)ばく露
A potential danger to those involved
in the production, Formulation and application of this systemic fungicide, seed protectant and wood preservative
環(huán)境運命予測
Biological. The sulfoxidation of carboxin to carboxin sulfoxide by the fungus Ustilago
maydis was reported by Bollag and Liu (1990).
Soil. Carboxin oxidized in soil forming carboxin sulfoxide. The half-life in soil was
reported to be 24 hours (Worthing and Hance, 1991).
Plant. In plants (barley, cotton and wheat) and water, carboxin oxidizes to the corresponding sulfoxide (Worthing and Hance, 1991).
代謝経路
Carboxin is a systemic fungicide which is very stable to hydrolysis but
is readily oxidised at sulfur to a sulfoxide and a sulfone. The latter,
oxycarboxin, is itself a commercial fungicide. Metabolism is mainly
by oxidation at sulfur in soil, plants and animals but hydroxylation of
the phenyl ring is also important in animals. Hydrolysis has been
convincingly demonstrated only in plants (peanut).
輸送方法
UN2588 Pesticides, solid, toxic, Hazard Class: 6.1;
Labels: 6.1-Poisonous materials, Technical Name Required.
不和合性
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions.
Keep away from alkaline materials, strong bases, strong acids,
oxoacids, epoxides. Avoid heat and humidity. Thermal decomposition products may include cyanide gas and cyanide salts.
廃棄物の処理
Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator
equipped with an afterburner and scrubber. All federal, state,
and local environmental regulations must be observed.
5,6-ジヒドロ-2-メチル-N-フェニル-1,4-オキサチイン-3-カルボアミド 上流と下流の製品情報
原材料
準備製品