(1R,3S)-3-[[(E)-4,5-ジヒドロ-2-オキソチオフェン-3(2H)-イリデン]メチル]-2,2-ジメチルシクロプロパンカルボン酸(5-ベンジル-3-フリル)メチル 価格 もっと(3)

メーカー	製品番號	製品説明	CAS番號	包裝	価格	更新時間	購入
富士フイルム和光純薬株式會社(wako)	W01ACSP-367S	カデスリン Kadethrine, 100 ug/mL in MeOH	58769-20-3	1mL	￥14200	2024-03-01	購入
富士フイルム和光純薬株式會社(wako)	W01ACSP-367N	カデトリン標(biāo)準(zhǔn)品 Kadethrine Standard	58769-20-3	10mg	￥14200	2024-03-01	購入
関東化學(xué)株式會社(KANTO)	49803-36	カデスリン標(biāo)準(zhǔn)品 Kadethrin standard	58769-20-3	100mg	￥33000	2024-07-01	購入

(1R,3S)-3-[[(E)-4,5-ジヒドロ-2-オキソチオフェン-3(2H)-イリデン]メチル]-2,2-ジメチルシクロプロパンカルボン酸(5-ベンジル-3-フリル)メチル 化學(xué)特性,用途語,生産方法

使用

Kadethrin is used to control household pests, particularly houseflies, mosquitoes and cockroaches. It is normally used in combination with other pyrethroid insecticides and synergists.

代謝経路

Kadethrin is used almost wholly indoors and therefore little has been published on its environmental fate. Information on its photodegradation and metabolism in rats has been reported.

Degradation

Kadethrin is unstable to heat and it is rapidly decomposed by light. It is hydrolysed in aqueous alkaline solution to (E)-(1R)-cis-2,2-dimethyl-3- (2-oxothiolan-3-ylidenemethyl)cyclopropanecarboxylic acid (2), 5-benzyl- 3-furylmethanol (3) and its thiolactone ring-opened derivative (5) (Scheme 1).
Products of photodecomposition have been reported by Ohsawa and Casida (1979). Photo-hydrolysis of kadethrin occurs on sunlight irradiation affording 2 and 5 and 5-benzyl-3-furancarboxylic acid (4), presumably via the alcohol (3). cis-trans Isomerisation of the cyclopropane ring and E-Z interconversion about the double bond was also noted. Thus, from the lRcisE isomer (kadethrin), all of the possible isomers were found to varying degrees (ie. 1RScis-trans-E-Z mixtures).
Photo-hydrolysis products (e.g. 2 and 5) were also found aS isomers. The facility of the isomerisation process was considered to be due to resonance stabilisation of a triplet diradical, one form of which (6) is shown in Scheme 1. Kadethrin also yielded a lactone (7) derived from the cyclopropane ring. Photo-oxidation of the alcohol moiety analogous to that reported for resmethrin was also found. The hydroxylactone (8) and the benzyloxylactone (9) were reported (but the hydroxycyclopetenolone [resmethrin, 61) was absent.

(1R,3S)-3-[[(E)-4,5-ジヒドロ-2-オキソチオフェン-3(2H)-イリデン]メチル]-2,2-ジメチルシクロプロパンカルボン酸(5-ベンジル-3-フリル)メチル 上流と下流の製品情報

原材料

準(zhǔn)備製品

(1R,3S)-3-[[(E)-4,5-ジヒドロ-2-オキソチオフェン-3(2H)-イリデン]メチル]-2,2-ジメチルシクロプロパンカルボン酸(5-ベンジル-3-フリル)メチル 生産企業(yè)

名前	電話番號	電子メール	國籍	製品カタログ	優(yōu)位度
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22963	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569266 15319487004	1015@dideu.com	China	3939	58
TargetMol Chemicals Inc.	+1-781-999-5354 +1-00000000000	marketing@targetmol.com	United States	32159	58
SUZHOU SENFEIDA CHEMICAL CO.,LTD	+86-0512-83500002 +8615195660023	sales@senfeida.com	China	26362	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	94657	76
Sichuan Kulinan Technology Co., Ltd	400-1166-196 18981987031	cdhxsj@163.com	China	11707	57
Shanghai JONLN Reagent Co., Ltd.	400-0066400 13621662912	422131432@qq.com	China	9978	55
TianJin Alta Scientific Co., Ltd.	022-65378550-8551	contact@altascientific.com	China	2773	58
Alta Scientific Co., Ltd.	022-6537-8550 15522853686	sales@altasci.com.cn	China	4511	55

58769-20-3((1R,3S)-3-[[(E)-4,5-ジヒドロ-2-オキソチオフェン-3(2H)-イリデン]メチル]-2,2-ジメチルシクロプロパンカルボン酸(5-ベンジル-3-フリル)メチル)キーワード:

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• 58769-20-3
• [1r-[1alpha,3alpha(e)]]-[5-(phenylmethyl)-3-furanyl]methyl3-[(dihydro-2-ox
• 1r,cis-ru15525
• 3-((dihydro-2-oxo-3(2h)-thienylidene)methyl)-2,2-dimethyl-,(5-(phenylmethyl)-3-furanyl)methylester,cyclopropanecarboxylicaci
• 5-benzyl-3-furylmethyl
• 5-benzyl-3-furylmethyl(+)-cis-(1r,3s,e)2,2-dimethyl-3-(2-oxo-2,3,4,5-tetrahydrothiophenylidenemethy
• 5-benzyl-3-furylmethyl(e)-(1r)-cis-2,2-dimethyl-3-(2-oxothiolan-3-ylidenemeth
• 5-benzyl-3-furylmethyl(e)-(1r,3s)-2,2-dimethyl-3-(2-oxothiolan-3-ylidenemethyl
• [5-(PHENYLMETHYL)-3-FURANYL]-METHYL-3-[(DIHYDRO-2-OXO-3(2H)-THIENYLIDENE) METHYL]-2,2-DIMETHYLCYCLOPROPANE
• [5-benzyl-3-furyl]methyl [1R-[1alpha,3alpha(E)]]-3-[(dihydro-2-oxo-3(2H)-thienylidene)methyl]-2,2-dimethylcyclopropanecarboxylate
• KADETHRIN PESTANAL 250 MG
• KADETHRIN PESTANAL
• Kadethrine
• KADETHRINE STANDARD
• (1R,3S)-3-[[(E)-4,5-Dihydro-2-oxothiophen-3(2H)-ylidene]methyl]-2,2-dimethylcyclopropanecarboxylic acid (5-benzyl-3-furyl)methyl ester
• 3-((dihydro-2-oxo-3(2h)-thienylidene)methyl)-2,2-dimethyl-,(5-(phenylmethyl)-3-furanyl)
• (1R,3S)-3-[(E)-(Dihydro-2-oxo-3(2H)-thienylidene)methyl]-2,2-dimethylcyclopropanecarboxylic acid [5-(phenylmethyl)-3-furanyl]methyl ester
• (5-(phenylmethyl)-3-furanyl)methylester,(1r-(1-alpha,3-alpha(e)))-imethyl
• )-cyclopropanecarboxylate
• cis-kadethrin
• cyclopropanecarboxylicacid,3-((dihydro-2-oxo-3(2h)-thienylidene)methyl)-2,2-d
• ent29117
• o-3(2h)-thienylidene)methyl]-2,2-dimethylcyclopropanecarboxylate
• ru15525
• spray-tox
• yl)cyclopropanecarboxylate.
• KADETHRIN
• UGWALRUNBSBTGI-ZKMZRDRYSA-N
• Kadethrine@100 μg/mL in Methanol
• Cyclopropanecarboxylic acid, 3-[(E)-(dihydro-2-oxo-3(2H)-thienylidene)methyl]-2,2-dimethyl-, [5-(phenylmethyl)-3-furanyl]methyl ester, (1R,3S)-
• AI3-29117
• カデトリン
• (1R,3S)-3-[[(E)-4,5-ジヒドロ-2-オキソチオフェン-3(2H)-イリデン]メチル]-2,2-ジメチルシクロプロパンカルボン酸(5-ベンジル-3-フリル)メチル
• カデスリン標(biāo)準(zhǔn)品
• カデスリン
• カデトリン標(biāo)準(zhǔn)品
• カデスリン, 100 μg/mL in MeOH
• (5-ベンジルフラン-3-イル)メチル (1R,3S)-2,2-ジメチル-3-{[(3E)-2-オキソチオラン-3-イリデン]メチル}シクロプロパン-1-カルボキシラート
• 農(nóng)薬類，殺蟲剤および除草剤など
• 生活関係標(biāo)準(zhǔn)物質(zhì)
• 食料品
• 有機標(biāo)準(zhǔn)物質(zhì)