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ChemicalBook >> CAS DataBase List >>DIETHYL DIBROMOMALONATE

DIETHYL DIBROMOMALONATE

CAS No.
631-22-1
Chemical Name:
DIETHYL DIBROMOMALONATE
Synonyms
Ethyl dibromomalonate;DIETHYL DIBROMOMALONATE;Diethyldibromomalonate,98%;Diethyl dibromomalonate 97%;Diethyl 2,2-dibromomalonate;iethyl2,2-dibromopropanedioate;diethyl 2,2-dibromopropanedioate;dibromo-propanedioicacidiethylester;Dibromo malonic acid, diethyl ester;1,3-diethyl 2,2-dibromopropanedioate
CBNumber:
CB9227354
Molecular Formula:
C7H10Br2O4
Molecular Weight:
317.96
MDL Number:
MFCD00015154
MOL File:
631-22-1.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02

DIETHYL DIBROMOMALONATE Properties

Boiling point 140-143 °C/18 mmHg (lit.)
Density 1.68 g/mL at 25 °C (lit.)
refractive index n20/D 1.484(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility sol benzene, CCl4, DMSO, THF
form liquid
color Clear, light yellow
BRN 1783879
FDA UNII 32T45AS5LZ
EPA Substance Registry System Propanedioic acid, dibromo-, diethyl ester (631-22-1)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314-H318
Precautionary statements  P260h-P301+P330+P331-P303+P361+P353-P305+P351+P338-P405-P501a
Risk Statements  34
Safety Statements  20-26-36/37/39-45-60
RIDADR  1760
WGK Germany  3
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29171900
NFPA 704
1
3 0

DIETHYL DIBROMOMALONATE price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 412708 Diethyl dibromomalonate 97% 631-22-1 25ml $71.4 2024-03-01 Buy
Alfa Aesar A11508 Diethyl dibromomalonate, 97% 631-22-1 5g $20.65 2024-03-01 Buy
Alfa Aesar A11508 Diethyl dibromomalonate, 97% 631-22-1 25g $46.65 2024-03-01 Buy
Alfa Aesar A11508 Diethyl dibromomalonate, 97% 631-22-1 100g $153.65 2024-03-01 Buy
Matrix Scientific 095005 Diethyl 2,2-dibromomalonate 95+% 631-22-1 100g $252 2021-12-16 Buy
Product number Packaging Price Buy
412708 25ml $71.4 Buy
A11508 5g $20.65 Buy
A11508 25g $46.65 Buy
A11508 100g $153.65 Buy
095005 100g $252 Buy

DIETHYL DIBROMOMALONATE Chemical Properties,Uses,Production

Uses

Diethyl dibromomalonate is used for selective bromination of polyunsaturated ester enolates; converts alkenes into cyclopropanes in the presence of suitable heavy metal reagents.

Preparation

Diethyl dibromomalonate is prepared in 95% yield by reaction of diethyl malonate with bromine.

General Description

Diethyl dibromomalonate reacts with sodium methoxide in cyclohexene to afford dibromonorcarane. It also reacts with allyl(pyridine)cobaloximes to afford the corresponding allyl-substituted esters.

storage

lachrymator; light sensitive. Store in the dark under nitrogen. This toxic reagent should be handled in a fume hood.

685-87-0
631-22-1
Synthesis of DIETHYL DIBROMOMALONATE from DIETHYL BROMOMALONATE

DIETHYL DIBROMOMALONATE Preparation Products And Raw materials

Global( 77)Suppliers
Supplier Tel Email Country ProdList Advantage
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29808 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21628 55
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5600 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Win-Win chemical CO., Limited
+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 14444 58
Shaanxi Didu New Materials Co. Ltd
+86-89586680 +86-13289823923 1026@dideu.com China 8808 58
Aladdin Scientific
tp@aladdinsci.com United States 57505 58
Qingdao Dexin Chemical Co., Ltd
+86-15553333686 +86-15553333686 15553333686@qq.com China 3113 58
Hebei Chuanghai Biotechnology Co., Ltd
+86-15350571055 +86-15350571055 Sibel@chuanghaibio.com China 6086 58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.
+8618950047208 ellena@amitychem.com China 43416 58

View Lastest Price from DIETHYL DIBROMOMALONATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
DIETHYL DIBROMOMALONATE pictures 2019-12-20 DIETHYL DIBROMOMALONATE
631-22-1
US $1.00 / KG 1KG 99% 100kg Career Henan Chemical Co
Dibromo malonic acid, diethyl ester dibromo-propanedioicacidiethylester Diethyl 2,2-dibromomalonate Ethyl dibromomalonate Malonic acid, dibromo-, diethyl ester Propanedioic acid, dibromo-, diethyl ester DIETHYL DIBROMOMALONATE 2,2-DIBROMO-MALONIC ACID DIETHYL ESTER Diethyldibromomalonate,98% Diethyl 2,2-dibromopropane-1,3-dioate Diethyl dibromomalonate 97% diethyl 2,2-dibromopropanedioate Propanedioic acid, 2,2-dibromo-, 1,3-diethyl ester iethyl2,2-dibromopropanedioate 1,3-diethyl 2,2-dibromopropanedioate 631-22-1 C7H10Br2O4 Br2CCO2C2H52 Esters Organic Building Blocks Carbonyl Compounds C6 to C7 Building Blocks C6 to C7 Carbonyl Compounds Esters