Potassium, (trimethylsilyl)- (9CI) Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
Trimethylsilylpotassium highly reactive nucleophile and one-electron transfer reagent; deoxygenates substituted epoxides with inversion of stereochemistry.
synthetische
Prepared quantitatively by the cleavage
of the silicon¨Csilicon bond of hexamethyldisilane with potassium hydride or potassium alkoxides (KOMe or potassium tbutoxide) (eqs 1 and 2). It can also be conveniently prepared by deprotonation of Me3SiH with KH (eq 3). These
procedures circumvent the need to handle volatile organomercury compounds that previous routes required.
Potassium, (trimethylsilyl)- (9CI) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
